ABS_394 Exam_3.3_Review.pdf

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Exam 3 Review

Preparation of carboxylic acids

 Oxidation of primary alcohols

 Oxidation of benzylic C-H bond:

 3. Ozonolysis of alkynes:

Phar

Problem

(YT

—

Ov”

Problem

—_——_>

Multistep Synthesis problems

Acidity

 Which hydrogen is more acidic? Ha or Hb.

 Rank the following compounds in order of increasing acidic strength.

Extraction

 Separate a mixture of benzoic acid and ethanol dissolved in dichloromethane.

Nomenclature and nucleophilic addition

 Rank the following compounds in order of increasing reactivity in nucleophilic addition

reaction.

A. 2-methyl-3-pentanone

B. Propanal

C. 2,4-dimethyl-3-pentanone

D. 2-methylpropanal

 Draw the product for the following reaction.