I have 2 questions and a table to be filled. Everything will be provided to work.

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thermodynamics__worksheet_vfall16_22.docx

PART 2: Dissolution of CaCl2

1. What is the balanced chemical equation for the dissolution of calcium chloride in water?

2. Proposed Initial Mass of CaCl2 to prepare 50 mL of 1M Solution:______________

Calculation of theoretical mass for a 1M solution in 50 mL water:

Table 4: Calcium Chloride Experimental Temperatures

Temperature

(ºC)

Time

(s)

Trial 1

Trial 2

0

15

30

45

60

75

90

105

120

135

150

165

180

Table 5: Calcium Chloride Experimental Data

Trial #1

Trial #2

Mass of CaCl2 (g)

Volume of Water (mL)

Mass of Water (g)

Initial temperature, Ti (ºC)

Final temperature, Tf (ºC)

3. Fill in the following tables with the experimental data and results for part two.

Table 6: Calcium Chloride Experimental Results

Trial #1

Trial #2

Mass of Solution (g)

∆T (ºC)

qsurr (J)

qsys (J)

Moles of CaCl2 (mol)

∆Hrxn (kJ/mol)

∆S◦rxn (J/mol∙K) from handout

∆Grxn (kJ/mol)

Average ∆Grxn (kJ/mol)

Arizona State University 1 School of Molecular Sciences