I would like someone to help me finish this Organic chemistry assignment in short time (during the next 12 hours)

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organic_assignment_6_2015.pdf

Organic Chemistry (CHM205) Assignment #6 Name: Due 12/12/15 1. Suppose the following molecules undergo a proton transfer reaction. Draw the

mechanism and give the most likely products. Be sure to include all mechanism arrows, electron pairs, and formal charges for all starting materials and products. Label the acid, base, conjugate acid, and conjugate base.

a. OLi HBr

b.

OH

NH3

c. OHS

2. Give the Keq expression for the reaction in question 1c. 3. Draw an energy diagram for the reaction in question 1c. Make sure label the axes, ΔG°, and ΔG . Provide the reactants, products, and transition state in the appropriate places. Is this a favorable reaction? Why or why not?

4. Which of the following molecules is more acidic? Explain your choice.

a.

O

H

F

OH

b.

O O

H

O

H

5. Rank the following compounds from most acidic (rank of 1) to least acidic (rank of 4). Explain your answer.

OH NH2 Br OH OH 6. Rank the following compounds in order of most basic to least basic. Explain your answer.