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    chem3001_ch2.docx
    Home>Chemistry homework help>Chemistry

    CHEM 3001 – Ch. 2 Quiz

    (1) Draw a 3dx2-y2 orbital. Denote axes and phasing. How many radial and angular nodes are in this orbital? What is the point group of this orbital?

    (2) What states are possible for a d3 configuration? Determine the Coulombic and exchange energies for each and rank the states in terms of relative energy.

    (3) According to Slater’s rules, a 3d electron in Ni has a higher effective nuclear charge than a 4s electron. Is the same true for early first row transition metals? Using Slater’s rules, calculates S and Z* for 4s and 3d electrons of Sc and Ti and comment on the similarities or differences with Ni.

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