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Experiment IV

Newtonian Cooling

EGME

Group members:

ABSTRACT

The objective of this experiment is to understand the relationship between the change of temperature of an object and its surroundings. The Newtonian Cooling says that the temperature of an object is proportional to the temperature of the surrounding. The reason for the experiment is to make an experiment that measures temperature using a transducer of our own choice, understand the heat transfer and determine the overall heat transfer coefficient. After finishing the experiment and calculating the data and graph them, we concluded that the area of the crucible was 33.53 by using either AutoCad or SolidWorks. Furthermore, the lead undergoes two phases and between these two phases there is a transition phase where the temperature stays constant for a period of time, which is between the 2nd and the 5th minute of the experiment. Point () turned out to be (17.0315,126.6141). And point () is (6.3648,301.5625). Moreover, then we got the heat transfer coefficient which is h = 2.6019.

TABLE OF CONTENTS

Abstract ……………………………………………………………………………2

Table of Contents…………………………………………………………………..3

Introduction and Theory……………………………………………………….......4-9

Procedures………………………………………………………………………..10-11

Summary of Important Results…………………………………………………….12

Sample Calculations and Error Analysis…………………………………………...13

Discussion and Conclusion…………………………………………………………14

References…………………………………………………………………………..15

Appendix…………………………………………………………………………16-19

INTRODUCTION AND THEORY

In this experiment, a mass of lead in a crucible will be heated to its melting point and a transducer will be inserted in the lead. The heating is then ceased and the data of temperature versus time are accumulated by some data-acquisition system of your choice.

It is known from thermodynamics that when two bodies at different temperatures are in contact, heat will flow from the hotter body to the cooler one in a process known as Heat Transfer. The rate of this heat flow depends upon the temperature difference and thermal resistances in much the same way that electric current depends upon the potential difference (voltage) and electrical resistances. In solids, heat transfer occurs by molecular motion in a process called conduction, whereas in fluids, such as air and water, heat is transferred by fluid motion in a process called convection. In addition, heat is also transferred by electromagnetic radiation in transparent substances, or in a vacuum.

Consider a solid object in contact with air. If the surface temperature of the body, , is higher than the air temperature, , then there will be heat transferred from the object to the air. Newton proposed that the rate of this heat transfer, q, is proportional to the surface area of the object, A, and the temperature difference, :

(IV-1)

where the constant of proportionality, h, is called the heat transfer coefficient. Equation (IV-1) is known as the Newton’s rate equation.

In Newton’s time, the actual mechanism whereby this heat transfer occurred was not well understood. Today, however, it is known that heat transfer from a surface involves convection and radiation, and that these two mechanisms occur in parallel. As a result, the total rate of heat transfer from the surface, q, is the sum of the parts due to convection, , and radiation,. Thus, from Eq. (IV-1),

(IV-2)

where,

= convective heat transfer coefficient

= effective radiative heat transfer coefficient

In convection, if the surface temperature of the body, , is higher than the air temperature, , then the air particles near the surface will also take on a higher temperature. This will reduce their density so they, in effect, become “lighter” than the air particles farther removed from the body; in turn, this causes them to drift upward and be replaced by cooler, more dense particles. In this way, the heat is transferred from the hotter surface to the cooler air by fluid motion in a process called free convection (as opposed to forced convection where the air is blown over the surface). For a sphere of diameter D, the convective heat transfer coefficient can be estimated from:

(IV-3)

where,

= conductivity of the air = 0.024

= average

T = average absolute surface temperature

= length parameter (0.5mm)

In radiation, the rate of heat transfer is actually proportional to the difference of temperatures to the fourth powers. However, as an approximation, the effective radiative heat transfer coefficient can be estimated from

(IV-4)

where,

T = average absolute surface temperature

= Stefan-Boltzman constant, 5.67E-8

= emissivity (0.8)

In terms of thermal resistance, Eq. (IV-1) can be written as

where is the convective and radiative thermal resistance. In reality, the heat transfer coefficients vary considerably over the surface area. In the above formulation, h represents the average heat transfer coefficient.

From the interior of the solid, heat is transferred to the surface by conduction. For a one-dimensional system this process is described by the Fourier Rate Equation:

(IV-5)

where k is the thermal conductivity of the material and x is the coordinate distance. If L is a certain characteristic length or dimension of the body, then Eq. (IV-5) can be written approximately as

(IV-6)

where = L/kA is the conductive thermal resistance, and Δ is a temperature difference within the body, where a typical temperature distribution is plotted above the body. The flow of heat from an interior point to the air can thus be represented by a series thermal network.

If the thermal conductivity of the body is quite high, as it is for metals, then would tend to be small compared to. This relative effect of conduction and convection is measured by the Biot Number, :

(IV-7)

Thus, if the Biot Number is much smaller than one, that is <<1, then << this implies that for all practical purposes the temperature, T, at an interior point can be considered the same everywhere in the body and on the surface. This observation, when Bi << 1, leads to an important analytical simplification is known as “lumped mass” analysis.

Consider the body having temperature T at some time t. The internal energy, U, of the body is then

U = mcT (IV-8)

where m is the mass of the body, and c is the specific heat. If q is the heat (or energy) leaving the body per unit time, then by the first law of thermodynamics, the (negative) time rate of change of U must equal q:

(IV-9)

But, according to Eq. (IV-1), q leaves the surface by convection and radiation, and by the assumption of “lumped mass” analysis, T = Ts). Hence, the substitution of Eqs (IV-1) and (IV-8) into Eq. (IV-9) yields

(IV-10)

which is the lumped-mass differential equation describing the change of temperature with time. If To is the initial temperature, then the initial condition for Eq. (IV-10) is T(0) = To. Notice that the left side of Eq. (IV-10) is in units of temperature over time; therefore, the right side must also have these units. Since Ta is a constant, Eq. (IV-10) can be written as

where tc = mc/hA is known as the time constant. The above equation can be written as follows:

(IV-11)

Integration of Eq. (IV-11) yields

or, after evaluating the constant of integration

(IV-12)

where T=T0 when t  0. Thus, the temperature decays exponentially

(IV-13)

From Eq. (IV-12) it can be seen that if a body undergoes Newtonian cooling (h is a constant), then a plot of ln (T - Ta)/(To - Ta) vs. time will produce a straight line with slope -1/tc . From Eq.(IV-13) it is seen that when t = tc, T - Ta will have changed from To - Ta by a factor of 1/e  37%, and that when t = 5tc, T has been reduced to within 1% of room temperature.

PROCEDURES

Lead

Figure: 1

First, we obtain the following equipment in order to setup our experiment: crucible, pipe clay triangle, tripod, Bunsen burner, lead and a heat resistant mat. After setting up the experiment as shown in figure 1, we double click to open the LabView software that was on the desktop. On LabView, click the run arrow. We measured the diameters and heights of the crucible to help us later calculate the volume of the crucible. Then we heat the crucible with the lead in it to a temperature of 400C. When a temperature of 400C is reached, we begin calculating data as the crucible is cooled by the room temperature. The experiment took from 20 to 30 minutes to be completed as the lead reached to a temperature of 100C. When the maximum temperature is reached, click the DATA box on LabView, to stop the time data collection. After finishing calculating data, we saved them into our flash drives to later use them.

SUMMARY OF IMPORTANT RESULTS

Figure 2: Temperature vs Time that shows the important phases and points

Figure 3: Plot that shows ln(T-T0)/(T0-Ta) vs. Time

SAMPLE CALCULATIONS AND ERROR ANALYSIS

New Values:

–Point 41

Time constant: (minutes) ≈ 640.002 (seconds)

Determined Average Heat Transfer Coefficient, h:

, mass of crucible (83grams) =0.083kg, Area (33.53)=0.021632, ,

h=

DISCUSSION AND CONCLUSION

After finishing the experiment and calculating the data and graph them, we concluded that the area of the crucible was 33.53. We determined this value by using SolidWorks or AutoCad. Also, from the data obtain from the experiment, we noticed that the lead undergoes two phases and between these two phases there a transition phase where the temperature stays constant for a period of time which is between the 2nd and the 5th minute of the experiment. Point () turned out to be (17.0315,126.6141) and point () is (6.3648,301.5625). Moreover, then we got the heat transfer coefficient was h = 2.6019.

Errors in any experiment are unavoidable. One can only try to reduce them as much as possible. Therefore, the errors in this experiment could be due to wrong calculations, mistake in taking measurements, or a wrong setup for the sample in the machine. These are the errors that could happen by the one doing the experiment. However, there are errors that are not related to the one doing the experiment. The machine itself could be old or hasn’t had the proper maintenance and that could cause errors. Not only the machine could cause errors, but also the samples could be not manufactured well.

REFERENCES

[1] CSUF EGME 306A Lab Manual

[2] http://amrita.vlab.co.in/?sub=1&brch=194&sim=354&cnt=2

[3]http://www2.warwick.ac.uk/fac/sci/physics/current/teach/module_home/px110/scripts/es4.pdf

[4] http://physics.kenyon.edu/people/schumacher/Physics110/NewtonLawCooling.pdf

APPENDIX

Time (min)

Internal Temperature of Lead Mass (oC)

0.0011

402.418

0.0315

399.7624

0.1981

390.466

0.3648

384.2675

0.5315

375.8545

0.6981

368.7702

0.8648

362.1292

1.0315

355.0468

1.1981

348.8509

1.3648

342.2142

1.5315

336.9063

1.6981

328.5052

1.8648

323.6432

2.0315

318.7827

2.1981

315.6905

2.3648

315.6905

2.5315

315.6905

2.6981

316.5739

2.8648

316.1322

3.0315

314.807

3.1981

316.1322

3.3648

314.807

3.5315

315.6905

3.6981

315.6905

3.8648

316.1322

4.0314

315.6905

4.1981

316.1322

4.3648

315.2487

4.5315

315.2487

4.6981

315.2487

4.8648

314.807

5.0315

313.9237

5.1982

313.0404

5.3648

312.1572

5.5315

309.9493

5.6981

309.5078

5.8648

308.1833

6.0315

305.976

6.1981

304.2105

6.3648

301.5625

6.5315

298.4739

6.6981

292.7397

6.8648

287.8894

7.0315

280.3968

7.1981

278.1938

7.3648

273.7889

7.5315

267.1838

7.6981

265.4229

7.8648

260.1414

8.0315

256.6212

8.1981

251.7821

8.3648

247.8237

8.5315

244.7454

8.6981

240.7881

8.8648

237.271

9.0315

233.3148

9.1981

230.2379

9.3648

226.2823

9.5315

224.5243

9.6981

218.811

9.8648

217.0531

10.0315

213.5371

10.1981

210.4606

10.3648

206.9444

10.5315

205.1861

10.6981

202.5486

10.8648

200.7901

11.0315

196.833

11.1981

193.7547

11.3648

192.8751

11.5315

188.9163

11.6981

186.2765

11.8648

184.0762

12.0315

181.4353

12.1981

177.913

12.3648

177.4726

12.5315

174.3895

12.6981

171.7459

12.8648

170.4238

13.0315

168.6606

13.1981

164.2507

13.3648

163.8096

13.5315

161.1621

13.6981

159.8379

13.8648

158.0719

14.0315

153.2125

14.1981

154.0963

14.3648

154.5382

14.5315

150.1178

14.6981

149.2332

14.8648

147.0211

15.0315

146.136

15.1981

143.9224

15.3648

140.8215

15.5315

141.7077

15.6981

139.0485

15.8648

137.7182

16.0315

135.9438

16.1981

134.1686

16.3648

133.2807

16.5315

131.0599

16.6981

129.7267

16.8648

129.7267

17.0315

126.6141

17.1981

123.9437

17.3648

124.834

17.5315

123.053

17.6981

121.271

17.8648

119.4879

18.0315

119.4879

18.1981

118.1499

18.3648

115.9185

18.5315

114.5788

18.6981

113.6853

18.8648

112.7915

19.0315

112.7915

19.1981

110.5558

19.3648

106.5265

19.5315

109.2134

19.6982

106.5265

19.8648

106.5265

20.0315

105.6303

20.1981

103.8367

20.3648

103.3881

20.5315

102.0419

20.6981

101.1439

20.8648

100.2456

21.0315

99.347

Plot Ɵ

6.364799999999997 6.5315 6.698099999999997 6.864799999999997 7.0315 7.198099999999997 7.364799999999997 7.5315 7.698099999999997 7.864799999999997 8.031500000000001 8.198099999999998 8.3648 8.531500000000001 8.698099999999998 8.8648 9.031500000000001 9.198099999999998 9.3648 9.531500000000001 9.698099999999998 9.8648 10.0315 10.1981 10.3648 10.5315 10.6981 10.8648 11.0315 11.1981 11.3648 11.5315 11.6981 11.8648 12.0315 12.1981 12.3648 12.5315 12.6981 12.8648 13.0315 13.1981 13.3648 13.5315 13.6981 13.8648 14.0315 14.1981 14.3648 14.5315 14.6981 14.8648 15.0315 15.1981 15.3648 15.5315 15.6981 15.8648 16.0315 16.1981 16.3648 16.5315 16.6981 16.8648 17.0315 17.1981 17.3648 17.5315 17.6981 17.8648 18.0315 18.1981 18.3648 18.5315 18.6981 18.8648 19.0315 19.1981 19.3648 19.5315 19.6982 19.8648 20.0315 20.1981 20.3648 20.5315 20.6981 20.8648 21.0315 0.0 -0.0138833558374357 -0.0401813035063078 -0.0629785087296968 -0.0992493490321587 -0.110168993491387 -0.132367037609412 -0.1666044202232 -0.175933435671863 -0.204447743797834 -0.223914776741158 -0.251309454152115 -0.274290203199285 -0.292533811274811 -0.316486664444342 -0.338267560817297 -0.363348417871295 -0.383299212376039 -0.409546578001858 -0.421436624845433 -0.461084242737513 -0.473606377152612 -0.499132579021619 -0.522015340884369 -0.548826303930464 -0.56250782146385 -0.583388001485993 -0.597555688294198 -0.630190491041075 -0.656335310347126 -0.663933294865821 -0.698862636829057 -0.722851152806879 -0.743295135293647 -0.768397930054661 -0.802890641493913 -0.807288228114772 -0.838628125962534 -0.866305511288066 -0.880440101558229 -0.89960686400289 -0.949217273210848 -0.954317687987095 -0.985489620984976 -1.001453177796997 -1.023147201617766 -1.085391185283324 -1.073778548280895 -1.068022411380224 -1.127150745690695 -1.139415088289386 -1.170759238673557 -1.183581050749204 -1.216386619615346 -1.264230573473675 -1.250322147793318 -1.292651321977761 -1.31451898231403 -1.344451620032924 -1.375322068619568 -1.391127559289697 -1.431789654942841 -1.45701877542095 -1.45701877542095 -1.518523313532556 -1.574483492029143 -1.555476492916884 -1.593867558274506 -1.633814414116566 -1.675449885610105 -1.675449885610105 -1.707871720311995 -1.764395929960248 -1.799933734955646 -1.824357359639232 -1.849400975340654 -1.849400975340654 -1.914935887128729 -2.045120553812535 -1.956453641017558 -2.045120553812535 -2.045120553812535 -2.07653392341976 -2.142531303677713 -2.159742151438176 -2.213243041136601 -2.250592315559515 -2.289404079030702 -2.329796994619727

Time (min)

ln(T-Tₐ)/(Tₒ-Tₐ)

Temperature vs. Time

Internal Temperature of Lead Mass (oC) 0.0011 0.0315 0.1981 0.3648 0.5315 0.6981 0.8648 1.0315 1.1981 1.3648 1.5315 1.6981 1.8648 2.031499999999999 2.1981 2.3648 2.531499999999999 2.6981 2.8648 3.031499999999999 3.1981 3.3648 3.531499999999999 3.6981 3.8648 4.0314 4.198099999999997 4.364799999999997 4.5315 4.698099999999997 4.864799999999997 5.0315 5.198199999999997 5.364799999999997 5.5315 5.698099999999997 5.864799999999997 6.0315 6.198099999999997 6.364799999999997 6.5315 6.698099999999997 6.864799999999997 7.0315 7.198099999999997 7.364799999999997 7.5315 7.698099999999997 7.864799999999997 8.031500000000001 8.198099999999998 8.3648 8.531500000000001 8.698099999999998 8.8648 9.031500000000001 9.198099999999998 9.3648 9.531500000000001 9.698099999999998 9.8648 10.0315 10.1981 10.3648 10.5315 10.6981 10.8648 11.0315 11.1981 11.3648 11.5315 11.6981 11.8648 12.0315 12.1981 12.3648 12.5315 12.6981 12.8648 13.0315 13.1981 13.3648 13.5315 13.6981 13.8648 14.0315 14.1981 14.3648 14.5315 14.6981 14.8648 15.0315 15.1981 15.3648 15.5315 15.6981 15.8648 16.0315 16.1981 16.3648 16.5315 16.6981 16.8648 17.0315 17.1981 17.3648 17.5315 17.6981 17.8648 18.0315 18.1981 18.3648 18.5315 18.6981 18.8648 19.0315 19.1981 19.3648 19.5315 19.6982 19.8648 20.0315 20.1981 20.3648 20.5315 20.6981 20.8648 21.0315 402.4179999999997 399.7624 390.466 384.2674999999999 375.8545 368.7701999999997 362.1292000000001 355.0468 348.8509 342.2142 336.9062999999997 328.5052 323.6431999999999 318.7826999999999 315.6905 315.6905 315.6905 316.5738999999999 316.1322 314.807 316.1322 314.807 315.6905 315.6905 316.1322 315.6905 316.1322 315.2487 315.2487 315.2487 314.807 313.9236999999997 313.0403999999999 312.1572 309.9493 309.5077999999999 308.1832999999999 305.9759999999997 304.2105 301.5625 298.4739 292.7397 287.8894 280.3967999999997 278.1938 273.7889 267.1838 265.4229 260.1413999999999 256.6211999999997 251.7821 247.8237 244.7454 240.7881 237.271 233.3148 230.2379 226.2823 224.5243 218.811 217.0531 213.5371 210.4606 206.9444 205.1861 202.5486 200.7901 196.833 193.7547 192.8751 188.9163 186.2765 184.0762 181.4353 177.913 177.4726 174.3895 171.7459 170.4238 168.6606 164.2507 163.8096 161.1621 159.8379 158.0719 153.2125 154.0963 154.5382 150.1178 149.2332 147.0211 146.136 143.9224 140.8215 141.7077 139.0485 137.7182 135.9438 134.1686 133.2807 131.0599 129.7267 129.7267 126.6141 123.9437 124.834 123.053 121.271 119.4879 119.4879 118.1499 115.9185 114.5788 113.6853 112.7915 112.7915 110.5558 106.5265 109.2134 106.5265 106.5265 105.6303 103.8367 103.3881 102.0419 101.1439 100.2456 99.347

Time (min)

Temperature (C)

1