Interaction to hazmat

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intercations_of_hazmat_unit_v.docx

1. EPA uses what regulation to ban the use of compounds containing hexavalent chromium in cooling towers for air conditioners?

Answer

TSCA

RCRA

EPCRA

FIFRA

4 points   

Question 2

1.  

What two chemicals can be used medicinally to cure dermatitis (from a bacterial/fungal origin) and eliminate or reduce effluent gases from many industrial sources?

Answer

Metallic nitrates and nitrites

Metallic sodium permanganate and potassium permanganate

Sodium hydroxide and hypochlorous acid

Phenol and phosgene

4 points   

Question 3

1.  

Which of the following statements regarding oxidation numbers is FALSE?

Answer

The oxidation number of a monoatomic ion is the same as its ionic charge, such that the oxidation number of calcium is +2.

Each oxygen in KMnO4 has an oxidation number of -2 and the oxidation number of K is +1; therefore, the oxidation number on Mn in this compound is +7.

The oxidation number of each atom in an element is zero, such that the oxidation number of Cl2 is +2.

H2S contains sulfur which as an oxidation number of -2.

4 points   

Question 4

1.  

What type of chlorinated organic compounds has largely displaced the use of calcium hypochlorite in home swimming pool sanitation products?

Answer

Bleach

Di- and tri-chloroisocyanuric acids

Chlorine dioxide

Ozone

4 points   

Question 5

1.  

Which of the following statements concerning bulk storage of ammonium nitrate is FALSE?

Answer

The height of the storage pile should be no higher than 36" from the roof or the supporting and spreader beams overhead.

Storage piles should be sized and arranged so that all material in the pile is moved out periodically.

Ammonium nitrate should not be accepted for storage when the temperature of the product exceeds 100 degrees Fahrenheit.

Blasting agents should never be stored in the same building.

4 points   

Question 6

1.  

Oxidizers react with all of the following EXCEPT:

Answer

fuels, oils, and sawdust.

coke and water.

lubricants and wood shavings.

vegetable fats and coal.

4 points   

Question 7

1.  

Calcium hypochlorite is known by what name when it is used as a disinfectant in swimming pools?

Answer

CHC

HTH

Multi-chlor

Clorox

4 points   

Question 8

1.  

What two chemicals reacted violently to destroy the S.S. Grandcamp and kill 600 people off the coast of Texas City, Texas?

Answer

Fuel oil and ammonium nitrate

Chromium oxychloride and potassium dichromate

Phenol and phosgene

Chlorine dioxide and sodium perchlorate

4 points   

Question 9

1.  

What material can be used as an anesthetic by dentists and as a component in explosives?

Answer

Trichloroisocyanuric acid

Sodium dioxide

Potassium chloride

Ammonium nitrate

4 points   

Question 10

1.  

Potassium dichromate is a strong oxidizer and therefore incompatible with which of the following substances?

Answer

Dilute acetic acid

Water and sodium hydroxide

Potassium hydroxide and water

Hydrochloric acid

4 points   

Question 11

1.  

Give some examples of the types of hazardous chemicals, specifically oxidizers, stored in homes (such as those stored under counters and sinks, in garages/basements and in pump houses/sheds).  Discuss the following: A)    What problems and dangerous situations can result from the improper storage and use (i.e., mixing them together, etc.) of these chemicals?  Describe potential hazardous material interactions. B)    What government agency and statutes/regulation(s) govern for the labeling and registration of these hazardous household products?

Answer

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30 points   

Question 12

1.  

All ammonium compounds, which contain an ammonium ion (NH4+) and a negative ion, are thermally unstable.  A. Discuss two ways that ammonium compounds decompose when they are heated. What chemical reaction is involved in the thermal decomposition of ammonium persulfate? B. What is the most likely reason OSHA requires ammonium nitrate to be segregated for sulfur or finely divided metals? Explain your answer. C. What is the most likely reason OSHA requires employers to protect flooring and handling areas in buildings against impregnation by ammonium nitrate and requires that the floors be constructed without open drains, traps, tunnels or pits into which molten ammonium nitrate could flow and be confined in the event of a fire?

Answer

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30 points   

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