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361_13_strengthening_mech_c.ppt

Materials Moments:

Arthur C—Food Containers

Lewis & Ray—Al Composites

Background image: http://images.iop.org/objects/ntw/news/10/4/9/image1.jpg

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Exam I

Friday 21 February

Covers Chapters 1 – 7

Review Questions posted on Canvas

Strengthening Mechanisms

Sections 7.8 – 7.13

Strengthening Metals

Underlying Principle for Strengthening Metals

  • Dislocations facilitate plastic deformation
  • Inhibiting (binding, stopping, slowing) dislocation motion makes metals stronger

Strengthening Metals:

(Ways to restrict dislocation motion)

Composition change:

  • Solid-solution strengthening (Diffusion)
  • Case hardening
  • Alloying
  • Solid-solution strengthening (Diffusion)
  • Alloying

Carburizing furnace

Image: http://heatingitup.files.wordpress.com/2011/12/carburizing-furnace.jpg

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City Steel Heat Treating Co.

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Case Hardening – Hard Case w/ tough core

Low-C Steels

(> 0.30% C):

Carburizing,

Nitriding,

Carbonitriding

Carburized depth of 0.030” to 0.050”

in 4 hours @ 1700°F

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Alloying

http://tankiialloy.en.made-in-china.com/offer/AqCnWidOrYcV/Sell-Copper-Nickel-Alloy-Strip.html

Cu-Ni Alloy

Cu-Ni Alloy

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Atoms diffuse to a location that reduces strain energy

Underlying principle:

f04_07_pg178.jpg

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f16_07_pg190

Fig. 7.17

Tensile strains

Solid-Solution Strengthening:
Smaller Substitutional Impurity

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f16_07_pg190

Solid-Solution Strengthening:
Larger Substitutional Impurity

Fig. 7.18

Compressive strains

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f16_07_pg190

2. Solid-Solution Strengthening:

Interstital Impurity

Fig. 7.18

Compressive strains

Fits in interstitial sites

f16_07_pg190.jpg

f16_07_pg190

2. Solid-Solution Strengthening:

Interstital Impurity

Fig. 7.18

Compressive strains

Fits in interstitial sites

f16_07_pg190.jpg

Strengthening metals:

How are dislocations bound in:

Solid-solution strengthening?

They seek sites near dislocations
to reduce lattice strains.

This stabilizes the lattice and discourages plastic deformation.

YouTube: Dislocation motion is analogous to the movement of caterpillar

How Solid-Solution strengthening

binds dislocations

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f16_07_pg190

Cu-Ni alloy:

Strength & Elongation Variation with

Ni content

Fig. 7.16

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Strengthening Metals

No Composition change:

  • Grain-size Reduction—

Polycrystalline metals

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Grain size reduction:
Dislocation motion at a grain boundary

Fig. 7.14

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Grain-size reduction

Dislocation Pile-ups at grain boundaries

Young Modulus and Yield Strength 2:11

Strengthening metals:

How do we reduce grain size?

Strengthening metals:

How are dislocations bound in:

Grain-size reduction?

It’s difficult for dislocations to move past a grain boundary

The more grain boundaries, the more difficult for dislocations to move metal is strengthened

Strengthening Metals:

(Ways to restrict dislocation motion)

  • Solid-solution strengthening (Diffusion)
  • Grain-size reduction
  • Strain Hardening

a.k.a. Work Hardening

a.k.a. Cold Working

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f05_07_pg179

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3. Strain Hardening
(Work Hardening)

(Cold Working)

Includes (but not limited to)

Drawing

Rolling

Peening—Strain hardened on surface only

Strain hardened throughout

No composition change

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Strain Hardening in Copper

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Cold Working

Example: Wire Drawing

YouTube: Wire Drawing

“2.Combined Drawing Machine SH-1” 0:20 - 0:45

YouTube: Drawing Process in Manufacturing / Aluminium tube Production

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Strain Hardening:

Example: Rolling

f16_07_pg190.jpg

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Cold Working

Example: Shot peening

f16_07_pg190.jpg

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Cold Working

Example: Shot peened surface

f16_07_pg190.jpg

Dislocation

Densities

Plastic

Deformation:

Stainless Steel

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Strengthening due

to Cold Work

Fig. 7.19

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Strengthening metals:

How are dislocations bound in:

Strain hardening?

f05_07_pg179

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Increasing the dislocation density

increases the number of dislocations

which can repel each other.

f05_07_pg179.jpg

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Plastic Deformation difficult

Dislocations can’t easily move

Metal is Strengthened

Strain Hardening

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Recovery, Recrystallization, &
Grain Growth

Sections 7.10 – 7.13

Reverse of Strengthening

Annealing:
Eliminates dislocations

1) Recovery

2) Recrystallization

3) Grain Growth

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Recrystallization 580ºC

Stages of Recrystallization and grain growth

33% Cold-worked brass

(Tm = 900-940ºC)

t = 3 sec

t = 0

t = 4 sec

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Grain size increases

Stages of Recrystallization and grain growth

Cold-worked brass

t = 8 sec (580ºC)

t = 15 min (580ºC)

t = 10 min (700ºC)

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Plastic Deformation:
Polycrystalline
Cold-worked Nickel

Before deformation After deformation

Fig. 7.11--170x photomicrograph

f11_07_pg186.jpg

Controlled annealing

Strain-relaxed buffers due to annealing in Silicon

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Recovery, Recrystallization,

and Grain Growth

Recovery (grains recover slightly from cold-working)

Recrystal-lization (new grains form)

Grain Growth (larger grains grow at expense of smaller)

See Fig. 7.22

f16_07_pg190.jpg

YouTube: Tensile Test on Work-Hardened Copper: necking effect

YouTube: Tensile Test on Annealed Copper

Compare these videos:

Take note of the knurled knob on the RHS

How do we
restore ductility
to work hardened metals?

Eliminate Dislocations!

Some little study aids follow

Review on your own:
When Strengthening metals:

How are dislocations bound in these cases?

Grain-size reduction

Solid Solution Strengthening

Strain hardening

Element Crystal structure Atomic radius

Fe BCC 0.124 nm

Cr BCC 0.125 nm

Al FCC 0.125 nm

N HCP 0.065 nm

a) N in Fe at 700°C b) N in Fe at 900°C

c) Cr in Fe at 700°C d) Cr in Fe at 900°C

e) Al in Fe at 700°C f) Al in Fe at 900°C

1. For which combination of metals do you expect solid solution strengthening to occur?

2. For which combination of metals do you expect diffusion to be the fastest?

Metallic xl Structures

Face-Centered Cubic (FCC)

Cu, Al, Ag, Au, Pb, Ni, Pt

Body-Centered Cubic (BCC)

Na, Fe, Cr, Mo, W

Hexagonal Close-Packed (HCP)

Ti, Zn, Cd, Co, Mg

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