Exam review
Materials Moments:
Jennifer H.–Water Bottles
Background image: http://images.iop.org/objects/ntw/news/10/4/9/image1.jpg
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The “Ferrari” of Steel Microstructures:
Martensite
More on Case Hardening
Carburizing:
Case can be much deeper
Somewhat lower hardness
Used on lower-alloy steels (less expensive)
Continuous processing (less expensive)
Nitriding
Thinner, harder case
Used on Higher-alloy steels (pricier)
Longer run timesoften more costly
Run at lower temperaturesless part distortion
Can have white, hard, brittle surface prone to cracking
Batch processing (pricier)
Carbonitriding: increases case hardenability to obtain martensitic structure
http://blog.eurotherm.com/blog/2010/07/08/what-is-the-cost-difference-between-carburizing-and-nitriding-2/:
The graph illustrates that some Nitrided steels have a higher surface hardness than Carburized steels but a lower overall total case-depth. The higher hardness comes from combining Nitrogen and alloying elements in the steel and usually for straight Nitriding you would use what is termed as an alloyed steel. For Carburized steels you would normally use a lower alloy steel (unless Vacuum or Low Pressure carburizing).
For basic components that require some improvement in material properties, generally the lower cost treatments are to harden and temper (through harden) or carburize to shallow depths. However, engineered components require more sophisticated processing that may result in additional costs but as previously explained this is more than offset by the increase in the material properties that result from the treatment. - See more at: http://blog.eurotherm.com/blog/2010/07/08/what-is-the-cost-difference-between-carburizing-and-nitriding-2/#sthash.1MEawtm9.dpuf
Typically the higher the alloy content of the steel, the higher the cost of the base material. The Nitriding process CAN be a more costly process to run based on batch processing and long cycle times. However, other benefits of the Nitrided process such as lower temperature giving less distortion, additional strength properties from an alloyed steel, higher hardness (can lead to higher wear resistance) and other material properties can help to offset these costs.
- See more at: http://blog.eurotherm.com/blog/2010/07/08/what-is-the-cost-difference-between-carburizing-and-nitriding-2/#sthash.1MEawtm9.dpuf
http://heattreatment.linde.com/international/web/lg/ht/like35lght.nsf/repositorybyalias/wp_cbrzg_10/$file/10.pdf:
Carbonitriding can be applied to low cost, low alloy steels. The com- bination of adding nitrogen as well as carbon to the case increases the case hardenability sufficiently to result in a martensitic case that would not be possible with pure carburizing.
http://www.twi-global.com/technical-knowledge/faqs/process-faqs/faq-what-is-carburising-carbonitriding/:
All three processes rely on the transformation of austenite into martensite on quenching. The increase in carbon content at the surface must be high enough to give a martensitic layer with sufficient hardness, typically 700HV, to provide a wear-resistant surface. The required carbon content at the surface after diffusion is usually 0.8 to 1.0%C. These processes can be carried out on a wide range of plain carbon steels, alloy steels and cast irons where the bulk carbon content is a maximum of 0.4% and usually less than 0.25%. Incorrect heat treatment can lead to oxidation or de-carburisation. Although a relatively slow process, carburising can be used as a continuous process and is suitable for high volume, surface hardening.
Carbonitriding is undertaken on a similar range of steels although the bulk carbon content can be as high as 0.4 to 0.5%. The process is particularly suited for hardening the surface of components that need a through-hardened core, such as gears and shafts. Carbonitriding is a modification of gas carburisation where ammonia is added to the methane or propane and is the source of nitrogen.
http://www.onviollc.com/email/onvio_ontech/ontech_0906_v2a.html:
Which heat treatment method is better for precision gears?
Both carburizing and nitriding are acceptable heat treating methods for precision gearing. Through engineering, development and testing, Onvio has determined that carburized gears offer critical advantages for precision gearboxes.
HARDNESS DEPTH & CORE STRENGTH Carburized gears feature a significantly deeper hardened layer whose hardness gradually decreases to the core hardness. This structure provides superior surface contact fatigue properties and ductility/impact resistance and strength of the core. In addition sufficient case depth obtained in the carburizing process is required as a needle roller bearing surface in the planet gears.
Nitrided gears can have a “white layer” on the surface which is very hard and brittle. If is not removed it can be prone to flaking and cracking leading to heavy surface fracture and gear failure. The hardened case depth is significantly thinner than in similar carburized gears and transitions to the core hardness immediately behind the case.
SURFACE HARDNESS While both technologies offer very good surface hardness, Onvio believes that the depth penetration of carburizing provides our customers with superior performance and reliability for their demanding applications.
http://www.citysteelht.com/surface_treatments.html:
SURFACE HARDENING – INDUCTION PROCESS
It is frequently desirable to harden only the surface of steels by simply changing their microstructure without altering the chemical composition of the surface layers. If steel contains sufficient carbon to respond to hardening, it is possible to harden the surface layers only by very rapid heating for a short period of time, thus conditioning the surface for hardening by quenching.
Hardenability—ability of steel to form martensite when quenched.
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Case hardening Techniques compared
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Elastic Deformation:
Stress vs. Strain
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t02_05_pg119.jpg
Linear Elastic Behavior:
Hooke’s Law
= E
- Stress is linearly proportional to strain
- Stiffness – E – resistance to elastic
deformation
Elasticity in Metals– Stiffness
http://spaceflight.esa.int/impress/text/education/Mechanical%20Properties/index.html
fig_06_11
Brittle Failure:
Tensile test of Nodular Graphite Cast Iron
Comparison of E values
t02_05_pg119
Types of Deformation
- Elastic
- Plastic
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t02_05_pg119.jpg
Plastic Deformation:
Permanent
Plastic (adj.)
1630s, "capable of shaping or molding"
from L. plasticus, from Gk. plastikos
"able to be molded, pertaining to molding,"
Plastic (adj.)
Main modern meaning, "synthetic product made from oil derivatives," first recorded 1909, coined by Leo Baekeland (see bakelite).
Counterculture slang: adjective meaning "false, superficial" (1963).
Plastic Deformation by Design
Plastically-formed paperclip
can behave elastically
Paper clip
under normal use
Plasticity by design
Radial profile segments
Formed by plastic deformation;
Behaves elastically
Binder Clip
Plastic deformation of Metals–Spring shape
Elastic deformation: Shock absorbers
Springs absorb shock transmitted from road to vehicle.
Plastic deformation of Metals
Galvanized steel
Chain link fence
Plastic deformation of Metals
Pipe bending
http://remstoolsusa.com/
Plastic deformation of Metals
Sterling Silver chain
Plastic deformation of Ceramics
Usually only at high temperature
Glassware fabricated plastically
http://www.launchphotography.com/Sawdust_Festival_2006.html
Plastic deformation of Ceramics
Usually only under high temperature
Ornate glassware fabricated plastically
http://www.etsy.com/listing/105177137/vintage-toothpick-holder-green-ornate
Plastic deformation of Plastics
Usually only under high temperature
Legos are thermoplastics
Plastic deformation of Ceramics Usually only under high temperature
Plastic deformation of Plastics
Thermoplastic
Motorcycle
helmet
http://www.jspowersports.com/vega_motorcycle_helmets.htm
Plastic Deformation by Accident
Mechanical Property:
Plasticity—permanent deformation
Paper clip
under abuse
Plasticity by accident
Street lamp damaged during storm
(Bridgeport, CN)
Plasticity by Accident: Plastic Spoon
http://i.imgur.com/Z9M46KF.jpg
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Plastic Deformation
- Plastic deformation – Permanent
- Yielding – onset of plastic deformation
- Yield strength – Stress at yield
(specified amount of strain).
t02_05_pg119
Stress-strain curve
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t02_05_pg119.jpg
Strength
Strength–stress at which
“something” happens
- Yield strength
- Tensile strength
- Fracture strength
Yield Strengths for Metal Alloys
Table 6.2
t02_05_pg119
Tensile Test
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t02_05_pg119.jpg
t02_05_pg119
Tensile Test
AlMgSi alloy ductile fracture
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t02_05_pg119.jpg
fig_06_11
fig_06_11
Engineering Stress-strain curve for typical metals
True Stress
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Question of the Day:
How does Ductility
relate to
Plastic Deformation?
Ductility
- % plastic strain at fracture
(after subtracting off elastic recovery)
Toughness
http://www.sciencedirect.com/science/article/pii/S014296120700988X
The effect of aging on crack-growth resistance and toughening mechanisms in human dentin
A material’s ability to absorb energy and plastically deform before fracture
(also, A material’s resistance to fracture when a crack is present)
“The effect of aging on crack-growth resistance and toughening mechanisms in human dentin”
Dentin—The main, calcareous part of a tooth, beneath the enamel and surrounding the pulp chamber and root canals.
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Hardness
Resistance to scratching, denting
http://www.hardnesstesters.com/Products/Accessories/Indenters.aspx
Brittle Deformation
http://jbo.wikipedia.org/wiki/File:Broken_glass.jpg
Brittle Deformation
Brittle—Little or no plastic deformation before failure
http://www.gowelding.com/met/pwht.htm
New Steel
Pressure Vessel
Failed during
Hydraulic Test
Improper heat
Treatment after
Welding (PWHT)
Need to consider the PWHT—post weld heat treatment—of welded steel fabrications. Need to temper the weld?
Brittle Materials
- Very little plastic deformation before failure
- Fracture strains <5%
Brittle Deformation
Cast Aluminum
Motorcycle Engine Cover
- Cast Iron
- Cast Aluminum
- Very Hard (Ultra High-C) Steel
Brittle Metals
Brittle Materials
mild steel: 0.16–0.29 wt% C
Cast Iron: 3.0-4.5 wt% C
(ductile)
(brittle)
(brittle)
fig_06_11
Brittle Failure:
Tensile test of Nodular Graphite Cast Iron
Cast iron tends to be brittle, except for malleable cast irons. With its relatively low melting point, good fluidity, castability, excellent machinability, resistance to deformation and wear resistance, cast irons have become an engineering material with a wide range of applications and are used in pipes, machines and automotive industry parts, such as cylinder heads (declining usage), cylinder blocks and gearbox cases (declining usage). It is resistant to destruction and weakening by oxidation (rust). Nodular graphite reduces stress concentrations because of its spherical shape.
Deformation on the atomic scale
- Elastic
- Plastic
- Brittle
Mechanical Property terms
- Elastic - Elasticity
- Plastic - Plasticity
- Stiff - Stiffness
- Ductile - Ductility
- Strong - Strength
- Brittle - Brittleness
- Tough - Toughness
- Hard - Hardness