Exam review

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361_09_casehardening_elasticity_c.ppt

Factors affecting diffusion rates

  • Concentration Gradient—driving force
  • Diffusing species & host material
  • Temperature

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Diffusing Host Metal T(oC) D (m2/s)

species

Fe a-Fe (BCC) 500 3.0 x 10-21

Fe a-Fe (BCC) 900 1.8 x 10-15

Fe g-Fe (FCC) 500 1.1 x 10-17

Fe g-Fe (FCC) 900 7.8 x 10-16

Which diffuses faster?

  • Fe through a-Fe at 500oC
  • Fe through a-Fe at 900oC
  • Fe through g-Fe at 500oC
  • Fe through g-Fe at 900oC

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How does
diffusion
affect material properties?

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It strengthens

Brass =

Alloy of Copper and Zinc

http://www.middleschoolchemistry.com/img/content/multimedia/chapter_3/lesson_2/brass_cylinder.jpg

http://www.matweb.com/reference/copper-alloys.aspx:

Strength
Solid solution strengthening of copper is a common procedure.  Small amounts of an alloying element added to molten copper will completely dissolve and form a homogeneous microstructure (a single phase).  At some point, additional amounts of the alloying element will not dissolve; the exact amount is dependent on the solid solubility of the particular element in copper.  When that solid solubility limit is exceeded, two distinct microstructures form with different compositions and hardnesses.  Copper by itself is relatively soft compared with common structural metals.  An alloy with tin added to copper is known as bronze; the resulting alloy is stronger and harder than either of the pure metals.  The same is true when zinc is added to copper to form alloys known as brass. It should be noted that neither 'brass' nor 'bronze' is a concrete, technical term.   Tin is more effective in strengthening copper than zinc, but is also more expensive and has a greater detrimental effect on the electrical and thermal conductivities than zinc.  Aluminum (forming alloys known as aluminum bronzes), Manganese, Nickel, and Silicon can also be added to strengthen copper.

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Brass

Copper

Zinc

Brass =

Stronger than either Copper or Zinc

Explanation in Chapter 7

http://images.fineartamerica.com/images-medium-large/copper-zinc-and-brass-andrew-lambert-photography.jpg

Strength
Solid solution strengthening of copper is a common procedure.  Small amounts of an alloying element added to molten copper will completely dissolve and form a homogeneous microstructure (a single phase).  At some point, additional amounts of the alloying element will not dissolve; the exact amount is dependent on the solid solubility of the particular element in copper.  When that solid solubility limit is exceeded, two distinct microstructures form with different compositions and hardnesses.  Copper by itself is relatively soft compared with common structural metals.  An alloy with tin added to copper is known as bronze; the resulting alloy is stronger and harder than either of the pure metals.  The same is true when zinc is added to copper to form alloys known as brass. It should be noted that neither 'brass' nor 'bronze' is a concrete, technical term.   Tin is more effective in strengthening copper than zinc, but is also more expensive and has a greater detrimental effect on the electrical and thermal conductivities than zinc.  Aluminum (forming alloys known as aluminum bronzes), Manganese, Nickel, and Silicon can also be added to strengthen copper.

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City Steel Heat Treating Co.

f16_07_pg190

Solid Diffusion Hardening:

Case Hardening  Hard Case w/ tough core

Low-C Steels

(> 0.30% C):

Carburizing,

Nitriding,

Carbonitriding

Carburized depth of 0.030” to 0.050”

in 4 hours @ 1700°F

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*

f16_07_pg190.jpg

What happens in the case: Steel = C + Fe

  • Add more C to the outer surface.
  • Interstitial C imposes lattice strains in Fe
  • Strains near dislocations can bind atoms and reduce deformation (see Ch. 7)

Carburizing—Solid Diffusion process

Begin at 1:35–2:40

YouTube: Vacuum Carburizing and Heat treating

Composition & processing affect material properties

Section 6.1-6.3
Mechanical Properties of Metals:

Elastic Deformation:
Stress-Strain behavior

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Image: http://images.iop.org/objects/phw/news/12/2/27/Fracture.jpg

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Mechanical Properties:

How will the object respond to an applied load (force)?

  • Stiffness
  • Ductility
  • Strength
  • Toughness
  • Hardness

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Tension

Compression

Shear

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Tensile Test

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Tensile Test

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Tensile Test

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Ductile Failure:

Tensile Test of AlMgSi alloy

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fig_06_11

Brittle Failure:
Tensile test of Nodular Graphite Cast Iron

Principles of
Stress and Strain

What is it good for?

Image: http://mdhomehealth.com/wp-content/uploads/2013/06/betterstress.jpg

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  • Normalize tensile tests
  • Measure intensity of a load

Stress is used to:

The
Ultimate
Chair Cushion Design

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Types of Deformation

  • Elastic
  • Plastic

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Elastic Deformation:
Recoverable

Elastic

By Design

Elastic deformation of Metals

Motorcycle

Shock absorber

http://upload.wikimedia.org/wikipedia/commons/thumb/1/10/R75-rear-shock.jpg/220px-R75-rear-shock.jpg

Elastic deformation of Ceramics

Fiber optic cable

Elastic deformation of Polymers

Shooting a

rubber band

http://rickischultz.files.wordpress.com/2009/09/rubber-band.jpg

Elastic deformation of Composites

Carbon-fiber

prosthetic legs

http://info.rogersathletic.com/get-strong/bid/62010/Muscle-Tendon-Springs

Elastic deformation of Composites

Diving Board

Elastic deformation of Composites

Diving Board

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Quantifying Elastic Deformation

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Hooke’s Law

  • Elastic deformation–Recoverable:

 = E 

  • Stiffness – E – resistance to elastic deformation

fig_06_11

Brittle Failure: Tensile test of Nodular Graphite Cast Iron

Comparison of E values

Plastic Deformation:
Permanent

plastic (adj.)

1630s, "capable of shaping or molding"

from L. plasticus, from Gk. plastikos "able to be molded, pertaining to molding,"

plastic (adj.)

Main modern meaning, "synthetic product made from oil derivatives," first recorded 1909, coined by Leo Baekeland (see bakelite).

Picked up in counterculture slang as an adj. meaning "false, superficial" (1963).

Mechanical Property:
Elasticity–recoverable deformation

Paper clip

under normal use

Mechanical Property:
Plasticity—permanent deformation

Paper clip

under abuse

Plasticity by design

Radial profile segments

Plasticity by accident

Street lamp damaged during storm

(Bridgeport, CN)

Formed by plastic deformation;
Behaves elastically

Binder Clip

Plastic deformation of Metals–Spring shape

Elastic deformation: Shock absorbers

Springs absorb shock transmitted from road to vehicle.

Plastic Deformation

  • Plastic deformation – Permanent
  • Yielding – onset of plastic deformation
  • Yield strength – Stress at yield

(specified amount of strain).

J = −D dC dx

 

J=-D

dC

dx

D = D0 exp −Qd RT

⎛

⎝ ⎜

⎞

⎠ ⎟

 

D=D

0

exp

-Q

d

RT

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