Exam review
Factors affecting diffusion rates
- Concentration Gradient—driving force
- Diffusing species & host material
- Temperature
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Diffusing Host Metal T(oC) D (m2/s)
species
Fe a-Fe (BCC) 500 3.0 x 10-21
Fe a-Fe (BCC) 900 1.8 x 10-15
Fe g-Fe (FCC) 500 1.1 x 10-17
Fe g-Fe (FCC) 900 7.8 x 10-16
Which diffuses faster?
- Fe through a-Fe at 500oC
- Fe through a-Fe at 900oC
- Fe through g-Fe at 500oC
- Fe through g-Fe at 900oC
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How does
diffusion
affect material properties?
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It strengthens
Brass =
Alloy of Copper and Zinc
http://www.middleschoolchemistry.com/img/content/multimedia/chapter_3/lesson_2/brass_cylinder.jpg
http://www.matweb.com/reference/copper-alloys.aspx:
Strength Solid solution strengthening of copper is a common procedure. Small amounts of an alloying element added to molten copper will completely dissolve and form a homogeneous microstructure (a single phase). At some point, additional amounts of the alloying element will not dissolve; the exact amount is dependent on the solid solubility of the particular element in copper. When that solid solubility limit is exceeded, two distinct microstructures form with different compositions and hardnesses. Copper by itself is relatively soft compared with common structural metals. An alloy with tin added to copper is known as bronze; the resulting alloy is stronger and harder than either of the pure metals. The same is true when zinc is added to copper to form alloys known as brass. It should be noted that neither 'brass' nor 'bronze' is a concrete, technical term. Tin is more effective in strengthening copper than zinc, but is also more expensive and has a greater detrimental effect on the electrical and thermal conductivities than zinc. Aluminum (forming alloys known as aluminum bronzes), Manganese, Nickel, and Silicon can also be added to strengthen copper.
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Brass
Copper
Zinc
Brass =
Stronger than either Copper or Zinc
Explanation in Chapter 7
http://images.fineartamerica.com/images-medium-large/copper-zinc-and-brass-andrew-lambert-photography.jpg
Strength Solid solution strengthening of copper is a common procedure. Small amounts of an alloying element added to molten copper will completely dissolve and form a homogeneous microstructure (a single phase). At some point, additional amounts of the alloying element will not dissolve; the exact amount is dependent on the solid solubility of the particular element in copper. When that solid solubility limit is exceeded, two distinct microstructures form with different compositions and hardnesses. Copper by itself is relatively soft compared with common structural metals. An alloy with tin added to copper is known as bronze; the resulting alloy is stronger and harder than either of the pure metals. The same is true when zinc is added to copper to form alloys known as brass. It should be noted that neither 'brass' nor 'bronze' is a concrete, technical term. Tin is more effective in strengthening copper than zinc, but is also more expensive and has a greater detrimental effect on the electrical and thermal conductivities than zinc. Aluminum (forming alloys known as aluminum bronzes), Manganese, Nickel, and Silicon can also be added to strengthen copper.
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City Steel Heat Treating Co.
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Solid Diffusion Hardening:
Case Hardening Hard Case w/ tough core
Low-C Steels
(> 0.30% C):
Carburizing,
Nitriding,
Carbonitriding
Carburized depth of 0.030” to 0.050”
in 4 hours @ 1700°F
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*
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What happens in the case: Steel = C + Fe
- Add more C to the outer surface.
- Interstitial C imposes lattice strains in Fe
- Strains near dislocations can bind atoms and reduce deformation (see Ch. 7)
Carburizing—Solid Diffusion process
Begin at 1:35–2:40
YouTube: Vacuum Carburizing and Heat treating
Composition & processing affect material properties
Section 6.1-6.3
Mechanical Properties of Metals:
Elastic Deformation:
Stress-Strain behavior
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Image: http://images.iop.org/objects/phw/news/12/2/27/Fracture.jpg
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Mechanical Properties:
How will the object respond to an applied load (force)?
- Stiffness
- Ductility
- Strength
- Toughness
- Hardness
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Tension
Compression
Shear
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Tensile Test
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Tensile Test
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Ductile Failure:
Tensile Test of AlMgSi alloy
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fig_06_11
Brittle Failure:
Tensile test of Nodular Graphite Cast Iron
Principles of
Stress and Strain
What is it good for?
Image: http://mdhomehealth.com/wp-content/uploads/2013/06/betterstress.jpg
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- Normalize tensile tests
- Measure intensity of a load
Stress is used to:
The
Ultimate
Chair Cushion Design
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Types of Deformation
- Elastic
- Plastic
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Elastic Deformation:
Recoverable
Elastic
By Design
Elastic deformation of Metals
Motorcycle
Shock absorber
http://upload.wikimedia.org/wikipedia/commons/thumb/1/10/R75-rear-shock.jpg/220px-R75-rear-shock.jpg
Elastic deformation of Ceramics
Fiber optic cable
Elastic deformation of Polymers
Shooting a
rubber band
http://rickischultz.files.wordpress.com/2009/09/rubber-band.jpg
Elastic deformation of Composites
Carbon-fiber
prosthetic legs
http://info.rogersathletic.com/get-strong/bid/62010/Muscle-Tendon-Springs
Elastic deformation of Composites
Diving Board
Elastic deformation of Composites
Diving Board
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Quantifying Elastic Deformation
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Hooke’s Law
- Elastic deformation–Recoverable:
= E
- Stiffness – E – resistance to elastic deformation
fig_06_11
Brittle Failure: Tensile test of Nodular Graphite Cast Iron
Comparison of E values
Plastic Deformation:
Permanent
plastic (adj.)
1630s, "capable of shaping or molding"
from L. plasticus, from Gk. plastikos "able to be molded, pertaining to molding,"
plastic (adj.)
Main modern meaning, "synthetic product made from oil derivatives," first recorded 1909, coined by Leo Baekeland (see bakelite).
Picked up in counterculture slang as an adj. meaning "false, superficial" (1963).
Mechanical Property:
Elasticity–recoverable deformation
Paper clip
under normal use
Mechanical Property:
Plasticity—permanent deformation
Paper clip
under abuse
Plasticity by design
Radial profile segments
Plasticity by accident
Street lamp damaged during storm
(Bridgeport, CN)
Formed by plastic deformation;
Behaves elastically
Binder Clip
Plastic deformation of Metals–Spring shape
Elastic deformation: Shock absorbers
Springs absorb shock transmitted from road to vehicle.
Plastic Deformation
- Plastic deformation – Permanent
- Yielding – onset of plastic deformation
- Yield strength – Stress at yield
(specified amount of strain).
€
J = −D dC dx
J=-D
dC
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D=D
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exp
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