Molecular Spectroscopy chemistry homework

27 .

ftm-A-x-k-m.r.mn 0-¥☐m , ¥-p, -d -¥Em§

10 -¥a . ¥ -a

/ → / Qana, b. *H=lÉ¥÷¥EÉ = . Cc ↳ Cos

21m¥ -d) ¥*-m•) '

-1¥ -a)4¥-4--0 X.im/-aXz--mk-a-#sd5-0

T

Translation calculate eigenstates et de Conant nodes)

ditmas 0

1÷÷÷÷¥÷¥ ./1¥:¥Y¥|-O =¥m• 0

-

-

-

-¥m ,

12=0 ⇒ Lz=o

_tÉm☐4 '" - ¥am↳"=o

= - L's"

normalization I -_I iii. iii."714¥;) -4 Lili -11%2=1 E-RE c÷=F£l"=EÉ) "Y÷÷÷÷¥)÷µ⇒"l÷¥:) M=2MA +MB

Q =L'E

a"=oE o -E)(¥;) =¥1 , - ¥93

Q%lmIm)k£ ,

- 2(M¥m)"I,-111m¥: 9-i -

-Mikki

Q5=(m⇒%1 , -11M¥)k9→ + (Tmt)

" 29-3

Q" ' E-CI

sym

a " F-c¥

asym

AM 0%-0-7 translational .

why no bending ? selection rule on=-4

IR sepeetnue peak. N-t ~ 3200cm

"

-2=-2- ICE loaoemt -⇐c-

- •

sooocent

w=F¥m -I-I- 1200am -1-0 -

Topic 5 . Raman speetnayy Mchale highor cooler perturbationheavy . 12 - ~ IT. D , S - E

① ¥cmtD=¥_zcn(⇒e→%m+<mlÑtDIn) assume only initial state is 1k>

.

-

Cnet> = Snk

ciiitu-z-h-fjle-iwkmtkmliot.lk>de now substance Éii into

-

① ag-a.in ?

3-ecintb-fg-zcn%De-iwn-mtmlwc.is/ng--#*Y-zne-iwnmt.cm/wT-Dlns.fIe-iwkntTn1niktDlk dtz

- a -

- - - -

.

Ciii a) = 1¥)%n|jéi%ñ↳mlÑHDIn>dt, →

go.tte-iwkn-zcnlw.tk/k7dtz -

1k>¥1 in>¥1m>

TPA f-

Im> THE -1k> Twa - - - . -2in>

h?¥ . -Ein>

tart - -1k> ¥1m>

Raman stokes anti stakes .

tinny -

F- - Em> -

g- - - Ein>

vh-wz-ii.im> "±Éi ,

1k>

ÑHD=-ñ£É(eiwi-k-iEF-p-e-iwik.fi#*yWHz)---UJ-E-(eiwa-4- .it#+o+e--iwa-4-tiE'aE-o)sn1WtW1k

> = -€n1ñE¥¥⇐'e±"" -¥kÉ÷!!¥É'e÷wik

<NIÑHDIK> = -±<m1ñEYn>e-ik-ireius-4-EEEEeikie-ia.at .

Umn

CIFHT-i-h-Y-z.nfje-iwnm-hle-mneiwzti-un.net"¥, ☒Jj '

e-iwkm-zfu-nkewi-z-llnke-iwikd-ktlmntlnk-TP.lt ÑummnnTank -

T.P.E.IT#nnUnic---Raman t.eu?::.::i..ciiiEts--i'-+)InUmnTenkJIe--iWnm-4e-iodide

,

e- "" de

,

✗J.jae-iwkn-ke-iwikdt.se →=÷÷7

[m⇒= - i-qp-zumnu-m.fi#e-ilWkm+WztWkm-wDtidy, ✗Ina -

+⇒ =¥Eumnñ÷+÷÷÷÷÷⇒ t , →

sw=¥¥÷É¥ÑEumnñnk

Raman : #-)In(ETIE.tn?I!u-Yk*-iE-imE.:::#E-E) ✗slw÷III