Molecular Spectroscopy chemistry homework

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Lecture5.pdf

Czuib - rotation math in>

Tn #e'IET.IE?m1k3-l/0eS1XusslXR">

II.u.ie?esmtEdlks=4oekXuskxrlutEXr7IXosSl&eS--so/ekxu' tulku"> Ide>ftp.IUE/XpeD--vib,Transi-uendephe

. riot oJ=I/

I i¥¥:÷¥÷÷ "

sina.eu/#rah7iIL.?aat-r

solekxvtutr.sn/Xviil0/eS--Sfdrdrxqr,4Ecr.rDucr.rl4dr.M Xu (R)

permanent =)drdetcr.NUCR.NO/eCr.R)=GeSelee-shekR) d .-pete .

home one <Xu > IUECRJIXU,>

nuderuelr) taylor expansion .

dipole UelR7=UelRe)t¥4R-Re) -1 hemoment It * O

@ - - '

lxoluecrstxv.is

=UlReixt Fekete ④ < Xu' IR-Relaisortlenerl

Edrlre to transition dipole .

x =

my Txu , HR-Re)lXw,>

c. 3.3 I -Eau)'s (atat) Attn>=#Intl> raising op Aln> =Tnln - I > Lang op. <xvlxln> xsxuslatatln> ⇒

xodrnlnty-sxplntlntD-rncxutn-lstrntiexvln.is orthenaml =Tn Su!n- I thtfv 's htt

00=11

selection rule . ① Terran dip FLIR to the permanent n'booster d.pete does net matter

0--0=0 asym

Sym← → →←→ 0€20 0=5-0

UCR)=O NIKKO

Q Owo LIFO 1 OR R X active

P I also homeunder diatonic maleate ill does not have ZR abs .

t l R ② ou =I l J-- o Q at the sometimeofIt

, OM-0,11

- l P c don't need permanent rib dipole>

MH . C3 electronic UB

na.>etq.io/exxvsixrs=imsaediffvenoE=lO,adown"PES . motorhomes#de" >this>her"> Tks

g " I'd " ">

smiuyk , uteteirtudr, isoekxuluelrslxwilrfeidxrtuek → Colette.>sxutcxriluncrllxr">Hes← sole.la/udUecr7txuxl/0e7=sxwl#erl/elXuD

transitions,

£-4 dipole Ueglkktfecrsmluelrlrfekr.RS troneg-oe-jdrofgcr.sk/BUdbfeIbR)

Ugelr)=UgeCRe)t2Lqe_frfr-Re)t - - - lXvlUgeCR3lXu =?*"¥a"÷:÷÷"me¥m

Frank -4XVIXv"> detains which 0 "

→U '

Condon tragic-en has the Largest probability .Footer ngelke) # O

'¥i÷i¥¥¥ .

D. pdgaeenic vibrations . µ . H . Zi 10.2 - F- Naomichi 3Ncard ,"Y '

3 card terrains is¥¥¥!Iy, 3. enad for nott.EE?mzeondforuetlinen 3N- 615) vibration for nonlinear

( linen)notate .