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Lead Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Date of issue: 12/15/2014 Revision date: 12/15/2014 Version: 1.1

EN (English US) Page 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Substance

CAS No : 7439-92-1

Formula : Pb

Synonyms : C.I. 77575, in massive state / elemental lead, in massive state / glover, in massive state

BIG no : 10073

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Solder Battery: component Construction Electrodes

1.3. Details of the supplier of the safety data sheet

GSC International, Inc. 1747 N. Deffer Drive Nixa, MO 65714 United States of America Tel: 417-374-7431 Fax: 417-374-7442 Email: [email protected]

1.4. Emergency telephone number

Country Organization/Company Address Emergency number

MEXICO Servicio de Informacion Toxicologica Sintox Tintoreto #32 Edif. a Desp. Col. Nochebuena Mixcoac México, D.F.

1 800 009 2800 +52 55 5611 2634 /+52 55 5598 9095

UNITED STATES OF AMERICA

American Association of Poison Control Centers 1-800-222-1222

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (GHS-US)

Acute Tox. 4 (Oral) H302 Acute Tox. 4 (Inhalation) H332 Carc. 1B H350 Repr. 1A H360 STOT RE 2 H373 Aquatic Acute 1 H400 Aquatic Chronic 1 H410

Full text of H-phrases: see section 16

2.2. Label elements

GHS-US labeling

Hazard pictograms (GHS-US) :

GHS07

GHS08

GHS09

Signal word (GHS-US) : Danger

Hazard statements (GHS-US) : H302+H332 - Harmful if swallowed or if inhaled H350 - May cause cancer H360 - May damage fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure

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H400 - Very toxic to aquatic life H410 - Very toxic to aquatic life with long lasting effects

Precautionary statements (GHS-US)

:

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe dust, fume P264 - Wash hands thoroughly after handling P270 - Do not eat, drink or smoke when using this product P273 - Avoid release to the environment P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P308+P313 - If exposed or concerned: Get medical advice/attention P314 - Get medical advice/attention if you feel unwell P501 - Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for empty clean containers which can be disposed of as non-hazardous waste

2.3. Other hazards

No additional information available

2.4. Unknown acute toxicity (GHS-US)

Not applicable

SECTION 3: Composition/information on ingredients

3.1. Substance

Name Product identifier % Classification (GHS-US)

Lead (Main constituent)

(CAS No) 7439-92-1 > 99,9 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 Carc. 1B, H350 Repr. 1A, H360 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Chronic 1, H410

Full text of H-phrases: see section 16

3.2. Mixture

Not applicable

4.1. Description of first aid measures

First-aid measures general : If you feel unwell, seek medical advice. IF exposed or concerned: Get medical advice/attention. Call a poison center/doctor/physician if you feel unwell.

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Not applicable. Call a poison center/doctor/physician if you feel unwell.

First-aid measures after skin contact : Not applicable. Wash skin with plenty of water.

First-aid measures after eye contact : Not applicable. Rinse eyes with water as a precaution.

First-aid measures after ingestion : Not applicable. Rinse mouth. Call a poison center/doctor/physician if you feel unwell.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries after inhalation : No effects known.

Symptoms/injuries after skin contact : No effects known.

Symptoms/injuries after eye contact : No effects known.

Symptoms/injuries after ingestion : No effects known.

Chronic symptoms : No effects known.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Adapt extinguishing media to the environment.

Unsuitable extinguishing media : No unsuitable extinguishing media known.

5.2. Special hazards arising from the substance or mixture

Fire hazard : DIRECT FIRE HAZARD. Non combustible.

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Explosion hazard

:

DIRECT EXPLOSION HAZARD. No data available on direct explosion hazard. INDIRECT EXPLOSION HAZARD. No data available on indirect explosion hazard.

Reactivity : On burning: formation of metallic fumes. Oxidizes on exposure to air.

5.3. Advice for firefighters

Precautionary measures fire : Exposure to fire/heat: keep upwind. Exposure to fire/heat: consider evacuation. Exposure to heat: have neighborhood close doors and windows.

Firefighting instructions : Dilute toxic gases with water spray. Take account of toxic fire-fighting water. Use water moderately and if possible collect or contain it.

Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment : Gloves. Protective clothing. See "Material-Handling" to select protective clothing.

Emergency procedures : Mark the danger area. No naked flames.

6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".

6.2. Environmental precautions

Avoid release to the environment. Prevent soil and water pollution. Prevent spreading in sewers. Notify authorities if product enters sewers or public waters.

6.3. Methods and material for containment and cleaning up

For containment : Not applicable. Collect spillage.

Methods for cleaning up : Recover mechanically the product. Pick-up the material. Take collected spill to manufacturer/competent authority. Notify authorities if product enters sewers or public waters.

Other information : Dispose of materials or solid residues at an authorized site.

6.4. Reference to other sections

For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Meet the legal requirements. Do not discharge the waste into the drain. Handle unclean empty containers as full ones. Observe strict hygiene. Measure the concentration in the atmosphere. Carry out operations in the open/under local exhaust/ventilation or with respiratory protection. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust, fume. Use only outdoors or in a well-ventilated area. Take all necessary technical measures to avoid or minimize the release of the product on the workplace. Limit quantities of product at the minimum necessary for handling and limit the number of exposed workers. Provide local exhaust or general room ventilation. Wear personal protective equipment. Floors, walls and other surfaces in the hazard area must be cleaned regularly.

Hygiene measures : Separate working clothes from town clothes. Launder separately. Do not eat, drink or smoke when using this product. Always wash hands after handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures : Does not require any specific or particular technical measures. Comply with applicable regulations.

Storage conditions : Store locked up. Store in a well-ventilated place. Keep cool.

Incompatible materials : Strong acids, strong bases and oxidation agents.

Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources.

Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. Strong acids. Strong bases.

Storage area : Meet the legal requirements.

Special rules on packaging : SPECIAL REQUIREMENTS: closing. correctly labeled. meet the legal requirements. Secure fragile packaging in solid containers.

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7.3. Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Lead (7439-92-1)

ACGIH ACGIH TWA (mg/m³) 0,05 mg/m³

ACGIH Remark (ACGIH) CNS & PNS impair

OSHA Not applicable

8.2. Exposure controls

Appropriate engineering controls : Provide adequate general and local exhaust ventilation. Ensure good ventilation of the work station.

Personal protective equipment : Protective goggles. Gloves.

Materials for protective clothing : GIVE EXCELLENT RESISTANCE: No data available. GIVE GOOD RESISTANCE: butyl rubber. PVC. GIVE LESS RESISTANCE: No data available. GIVE POOR RESISTANCE: No data available.

Hand protection : protective gloves.

Eye protection : Safety glasses.

Skin and body protection : Not required for normal conditions of use.

Respiratory protection : Wear respiratory protection.

Environmental exposure controls : Avoid release to the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Solid

Appearance : Metal.

Molecular mass : 207,20 g/mol

Color : White to blue-grey

Odor : Odorless

Odor threshold : No data available

pH : No data available

Relative evaporation rate (butyl acetate=1) : No data available

Melting point : 327 °C

Freezing point : No data available

Boiling point : 1740 °C

Flash point : Not applicable

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : < 0,1 hPa

Relative vapor density at 20 °C : No data available

Relative density : 11,3

Specific gravity / density : 11340 kg/m³

Solubility : insoluble in water. Substance sinks in water. Soluble in nitric acid. Insoluble in organic solvents. Water: < 0,1 g/100ml

Log Pow : 0,73 (Estimated value)

Log Kow : No data available

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Viscosity, kinematic

:

Not applicable

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Explosive limits : No data available

9.2. Other information

VOC content : Not applicable (inorganic)

SECTION 10: Stability and reactivity

10.1. Reactivity

On burning: formation of metallic fumes. Oxidizes on exposure to air.

10.2. Chemical stability

Unstable on exposure to air.

10.3. Possibility of hazardous reactions

No additional information available

10.4. Conditions to avoid

No additional information available

10.5. Incompatible materials

Acids. Bases.

10.6. Hazardous decomposition products

Thermal decomposition generates : fume.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Oral: Harmful if swallowed. Inhalation: Harmful if inhaled.

Lead ( \f )7439-92-1

LD50 oral rat > 2000 mg/kg body weight (Rat; Weight of evidence)

LD50 dermal rat > 2000 mg/kg body weight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity)

ATE US (oral) 500,000 mg/kg body weight

ATE US (gases) 4500,000 ppmV/4h

ATE US (vapors) 11,000 mg/l/4h

ATE US (dust, mist) 1,500 mg/l/4h

Additional information Lead massive metal is not considered to be acutely toxic. It is not easily inhaled or ingested, and if it is accidentally ingested normally passes through the gastrointestinal system without significant absorption into the body. Lead is not easily absorbed through the skin.

Skin corrosion/irritation : Not classified

(Based on available data, the classification criteria are not met)

Serious eye damage/irritation : Not classified

(Based on available data, the classification criteria are not met)

Respiratory or skin sensitization : Not classified

(Based on available data, the classification criteria are not met)

Germ cell mutagenicity : Not classified

(Based on available data, the classification criteria are not met)

Carcinogenicity : May cause cancer.

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Lead (7439-92-1)

Additional information There is some evidence that inorganic lead compounds may have a carcinogenic effect, and they have been classified by IARC as probably carcinogenic to humans. However, it is considered that this classification does not apply to lead in articles, given the very low bioavailability of metallic lead. Carcinogenicity studies of lead metal powder have been negative. Epidemiology studies of workers exposed to inorganic lead compounds have found a limited association with stomach cancer. IARC has concluded that lead metal is possibly carcinogenic to humans (Group aB).

IARC group 2B - Possibly carcinogenic to humans

National Toxicology Program (NTP) Status 3 - Reasonably anticipated to be Human Carcinogen

Reproductive toxicity

:

May damage fertility or the unborn child.

Specific target organ toxicity (single exposure) : Not classified

(Based on available data, the classification criteria are not met)

Specific target organ toxicity (repeated exposure)

: May cause damage to organs through prolonged or repeated exposure.

Lead (7439-92-1)

Additional information Lead is a cumulative poison and may be absorbed into the body through ingestion or inhalation. Although inhalation and ingestion of lead in massive form are unlikely, poor hygiene practises may result in hand to mouth transfer which maybe significant over a prolonged period of time. Inorganic lead compounds have been documented in observational human studies to produce toxicity in multiple organ systems and body function including the haemotopoetic (blood) system, kidney function, reproductive function and the central nervous system.

Aspiration hazard : Not classified

(Based on available data, the classification criteria are not met)

Symptoms/injuries after inhalation : No effects known.

Symptoms/injuries after skin contact : No effects known.

Symptoms/injuries after eye contact : No effects known.

Symptoms/injuries after ingestion : No effects known.

Chronic symptoms : No effects known.

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : Dangerous for the environment. Very toxic to aquatic life with long lasting effects.

Ecology - air : Not dangerous for the ozone layer (Regulation (EC) No 1005/2009). Not included in the list of fluorinated greenhouse gases (Regulation (EC) No 842/2006). TA-Luft Klasse 5.2.2/II.

Ecology - water : No water pollutant (surface water). Maximum concentration in drinking water: 0.010 mg/l (lead) (Directive 98/83/EC). Highly toxic to aquatic organisms.

Lead (7439-92-1)

LC50 fish 1 2,8 (0,44 - 542) mg/l (96h) Coughlan, D.J., S.P. Gloss, and J. Kubota 1986. Acute and Sub-Chronic Toxicity of Lead to the Early Life Stages of Small mouth Bass (Micropterus dolomieui). Water Air Soil Pollut. 28(3/4):265-275

EC50 Daphnia 1 4,46 (0,53 - 5,1) mg/l (48h) Govindarajan, S., C.P. Valsaraj, R. Mohan, V. Hariprasad, and R. Ramasubramanian 1993. Toxicity of Heavy Metals in Aquaculture Organisms: Penaeus indicus, Perna viridis, Artemia salina and Skeletonema costatum. Pollut.Res. 12(3):187-189

12.2. Persistence and degradability

Lead (7439-92-1)

Persistence and degradability Biodegradability: Not applicable. No (test)data available on mobility of the substance.

ThOD Not applicable (inorganic)

12.3. Bioaccumulative potential

Lead (7439-92-1)

Log Pow 0,73 (Estimated value)

Bioaccumulative potential Low bioaccumulation potential (Log Kow < 4).

12.4. Mobility in soil

No additional information available

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12.5. Other adverse effects

Effect on ozone layer :

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Reuse or recycle following decontamination. Remove to an authorized dump (Class I). Do not discharge into surface water (2000/60/EC, Council decision 2455/2001/EC, O.J. L331 of 15/12/2001).

Additional information : LWCA (the Netherlands): KGA category 05. Hazardous waste according to Directive 2008/98/EC.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN3077 Environmentally hazardous substances, solid, n.o.s. Lead(7439-92-1), 9, III

UN-No.(DOT) : UN3077

Proper Shipping Name (DOT) : Environmentally hazardous substances, solid, n.o.s.

Lead(7439-92-1)

Department of Transportation (DOT) Hazard Classes

: 9 - Class 9 - Miscellaneous hazardous material 49 CFR 173.140

Hazard labels (DOT) : 9 - Class 9 (Miscellaneous dangerous materials)

DOT Symbols : G - Identifies PSN requiring a technical name

Packing group (DOT) : III - Minor Danger

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DOT Special Provisions (49 CFR 172.102)

:

8 - A hazardous substance that is not a hazardous waste may be shipped under the shipping description “Other regulated substances, liquid or solid, n.o.s.”, as appropriate. In addition, for solid materials, special provision B54 applies. 146 - This description may be used for a material that poses a hazard to the environment but does not meet the definition for a hazardous waste or a hazardous substance, as defined in 171.8 of this subchapter, or any hazard class as defined in Part 173 of this subchapter, if it is designated as environmentally hazardous by the Competent Authority of the country of origin, transit or destination. 335 - Mixtures of solids that are not subject to this subchapter and environmentally hazardous liquids or solids may be classified as “Environmentally hazardous substances, solid, n.o.s,” UN3077 and may be transported under this entry, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Each transport unit must be leak-proof when used as bulk packaging. A112 - Notwithstanding the quantity limits shown in Column (9A) and (9B) for this entry, the following IBCs are authorized for transportation aboard passenger and cargo-only aircraft. Each IBC may not exceed a maximum net quantity of 1,000 kg: a. Metal: 11A, 11B, 11N, 21A, 21B and 21N b. Rigid plastics: 11H1, 11H2, 21H1 and 21H2 c. Composite with plastic inner receptacle: 11HZ1, 11HZ2, 21HZ1 and 21HZ2 d. Fiberboard: 11G e. Wooden: 11C, 11D and 11F (with inner liners) f. Flexible: 13H2, 13H3, 13H4, 13H5, 13L2, 13L3, 13L4, 13M1 and 13M2 (flexible IBCs must be sift-proof and water resistant or must be fitted with a sift-proof and water resistant liner). B54 - Open-top, sift-proof rail cars are also authorized. IB8 - Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). IP3 - Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. N20 - A 5M1 multi-wall paper bag is authorized if transported in a closed transport vehicle. T1 - 1.5 178.274(d)(2) Normal............. 178.275(d)(2) TP33 - The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter.

DOT Packaging Exceptions (49 CFR 173.xxx) : 155

DOT Packaging Non Bulk (49 CFR 173.xxx) : 213

DOT Packaging Bulk (49 CFR 173.xxx) : 240

DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27)

: No limit

DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75)

: No limit

DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel.

Additional information

Other information : No supplementary information available.

ADR

No additional information available

Transport by sea

UN-No. (IMDG) : 3077

Proper Shipping Name (IMDG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

Class (IMDG) : 9 - Miscellaneous dangerous compounds

Packing group (IMDG) : III - substances presenting low danger

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Air transport

UN-No.(IATA) : 3077

Proper Shipping Name (IATA) : Environmentally hazardous substance, solid, n.o.s.

Class (IATA) : 9 - Miscellaneous Dangerous Goods

Packing group (IATA) : III - Minor Danger

SECTION 15: Regulatory information

15.1. US Federal regulations

Lead (7439-92-1)

Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 Not listed on the United States SARA Section 313

RQ (Reportable quantity, section 304 of EPA's List of Lists) 10 lb

15.2. International regulations

CANADA No additional information available

EU-Regulations No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP] Repr. 1A H360Df Acute Tox. 4 (Inhalation) H332 Acute Tox. 4 (Oral) H302 STOT RE 2 H373 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 Full text of H-phrases: see section 16

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Repr.Cat.1; R61 Repr.Cat.3; R62 Xn; R20/22 R33 N; R50/53

Full text of R-phrases: see section 16

15.2.2. National regulations

Lead (7439-92-1)

Listed on IARC (International Agency for Research on Cancer) Listed as carcinogen on NTP (National Toxicology Program)

\

15.3. US State regulations No additional information available

SECTION 16: Other information

Revision date : 12/15/2014

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Full text of H-phrases:

------ Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4

------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4

------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1

------ Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category 1

------ Carc. 1B Carcinogenicity Category 1B

------ Repr. 1A Reproductive toxicity Category 1A

------ STOT RE 2 Specific target organ toxicity (repeated exposure) Category 2

------ H302 Harmful if swallowed

------ H332 Harmful if inhaled

------ H350 May cause cancer

------ H360 May damage fertility or the unborn child

------ H373 May cause damage to organs through prolonged or repeated exposure

------ H400 Very toxic to aquatic life

------ H410 Very toxic to aquatic life with long lasting effects

NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given.

NFPA fire hazard : 0 - Materials that will not burn.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water.

HMIS III Rating

Health : * Chronic Hazard - Chronic (long-term) health effects may result from repeated overexposure

Flammability : 0 Minimal Hazard

Physical : 0 Minimal Hazard

Personal Protection : B

SDS US (GHS HazCom 2012)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requiremen ts only. It should not therefore be construed as guaranteeing any specific property of the product