Kinetics lab report turnitin

KineticsofBrominationofAcetone4.xlsx

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Data

CHEM2201/6201: Kinetics of the Bromination of Acetone
Time / s	[Br2] / mol L-1	Absorbance	Cuvette length (cm)	Epsilon (Lmol-1cm-1)
30.00	.00077	0.134	1	175
60.00	.00046	0.081	1	175
90.00	.00014	0.024	1	175
120.00	.00004	0.007	1	175
150.00	.00006	0.01	1	175
180.00	.00005	0.009	1	175
210.00	.00006	0.011	1	175
240.00	.00006	0.01	1	175
330.00	.00007	0.012	1	175
360.00	.00006	0.011	1	175
390.00	.00006	0.01	1	175
420.00	.00007	0.013	1	175
450.00	.00007	0.013	1	175
480.00	.00007	0.013	1	175
510.00	.00007	0.013	1	175

&T&D

&8Worksheet by Michael Batley &"Symbol,Regular"&8Ó&"Arial,Regular" School of Chemistry Macquarie University

Working

CHEM2201/6201: Kinetics of the Bromination of Acetone

[Br2] / mol L-1

Time / s

[Br2] / mol L-1

ln([Br2] / mol L-1)

1/[Br2] / mol L-1

dxy

dx2

syx

error

lny

dxy

dx2

syx

error

1/y

dxy

dx2

syx

error

.001

7.66E-04

-7.17E+00

1.31E+03

-1.49E-01

5.66E+04

2.13E-07

350E-6

3.04E-04

5.86E-07

1.01E+01

3.04E+02

-7.27E+01

-8.17E+01

7.35E+03

1.50E-01

214.7E-3

-7.30E+00

3.44E-13

1.32E+01

3.96E+02

1.73E+04

5.66E+03

1.89E+02

7.10E+02

111.1E+0

1.30E+03

4.63E-04

-7.68E+00

2.16E+03

-6.69E-02

4.33E+04

3.23E-08

350E-6

2.83E-04

2.14E-07

3.70E+00

2.22E+02

-2.84E+01

-2.32E+00

3.49E+01

1.25E-01

355.1E-3

-7.49E+00

4.59E-14

1.76E+00

1.06E+02

3.81E+03

3.43E+04

1.21E+03

1.67E+04

304.2E+0

2.26E+03

1.37E-04

-8.89E+00

7.29E+03

7.46E-04

3.17E+04

1.58E-08

350E-6

2.63E-04

1.88E-08

3.25E-01

2.92E+01

-2.89E+00

-1.53E+01

3.55E+02

4.69E-01

1.198E+0

-7.69E+00

3.54E-16

1.36E-02

1.22E+00

9.91E+01

4.49E+03

4.30E+01

2.26E+05

3.465E+3

3.22E+03

120

4.00E-05

-1.01E+01

2.50E+04

1.50E-02

2.19E+04

4.09E-08

350E-6

2.42E-04

1.60E-09

2.76E-02

3.32E+00

-2.80E-01

-4.62E+00

1.10E+02

1.38E-01

4.109E+0

-7.89E+00

2.56E-18

9.84E-05

1.18E-02

2.46E+00

2.00E+02

7.32E-01

4.27E+04

40.73E+3

4.18E+03

150

5.71E-05

-9.77E+00

1.75E+04

9.93E-03

1.39E+04

2.71E-08

350E-6

2.22E-04

3.27E-09

5.64E-02

8.46E+00

-5.51E-01

-1.21E+01

4.89E+02

1.59E-01

2.876E+0

-8.09E+00

1.07E-17

4.10E-04

6.15E-02

7.17E+00

7.66E+02

5.54E+00

6.27E+04

19.96E+3

5.14E+03

180

5.14E-05

-9.88E+00

1.94E+04

7.91E-03

7.74E+03

2.25E-08

350E-6

2.01E-04

2.64E-09

4.57E-02

8.23E+00

-4.51E-01

-1.35E+01

6.92E+02

1.15E-01

3.196E+0

-8.29E+00

7.00E-18

2.69E-04

4.84E-02

5.23E+00

7.09E+02

5.75E+00

4.79E+04

24.64E+3

6.09E+03

210

6.29E-05

-9.67E+00

1.59E+04

4.55E-03

3.36E+03

1.39E-08

350E-6

1.81E-04

3.95E-09

6.83E-02

1.43E+01

-6.61E-01

-2.30E+01

1.60E+03

9.65E-02

2.615E+0

-8.49E+00

1.56E-17

6.00E-04

1.26E-01

9.55E+00

1.53E+03

1.86E+01

4.71E+04

16.49E+3

7.05E+03

240

5.71E-05

-9.77E+00

1.75E+04

2.36E-03

7.84E+02

1.07E-08

350E-6

1.60E-04

3.27E-09

5.64E-02

1.35E+01

-5.51E-01

-2.37E+01

1.89E+03

6.65E-02

2.876E+0

-8.68E+00

1.07E-17

4.10E-04

9.84E-02

7.17E+00

1.36E+03

1.74E+01

3.69E+04

19.96E+3

8.01E+03

330

6.86E-05

-9.59E+00

1.46E+04

-4.51E-03

3.84E+03

9.28E-10

350E-6

9.90E-05

4.70E-09

8.12E-02

2.68E+01

-7.79E-01

-4.69E+01

6.06E+03

7.73E-03

2.397E+0

-9.28E+00

2.21E-17

8.50E-04

2.80E-01

1.24E+01

3.31E+03

7.46E+01

1.16E+04

13.86E+3

1.09E+04

360

6.29E-05

-9.67E+00

1.59E+04

-7.22E-03

8.46E+03

2.47E-10

350E-6

7.86E-05

3.95E-09

6.83E-02

2.46E+01

-6.61E-01

-4.55E+01

6.27E+03

2.65E-03

2.615E+0

-9.48E+00

1.56E-17

6.00E-04

2.16E-01

9.55E+00

2.84E+03

6.39E+01

9.89E+03

16.49E+3

1.18E+04

390

5.71E-05

-9.77E+00

1.75E+04

-1.03E-02

1.49E+04

9.46E-13

350E-6

5.81E-05

3.27E-09

5.64E-02

2.20E+01

-5.51E-01

-4.31E+01

6.26E+03

5.01E-04

2.876E+0

-9.68E+00

1.07E-17

4.10E-04

1.60E-01

7.17E+00

2.35E+03

5.20E+01

9.02E+03

19.96E+3

1.28E+04

420

7.43E-05

-9.51E+00

1.35E+04

-1.02E-02

2.31E+04

1.34E-09

350E-6

3.77E-05

5.52E-09

9.54E-02

4.00E+01

-9.07E-01

-7.04E+01

1.26E+04

1.28E-02

2.213E+0

-9.87E+00

3.05E-17

1.17E-03

4.92E-01

1.58E+01

5.44E+03

1.75E+02

1.09E+02

11.81E+3

1.38E+04

450

7.43E-05

-9.51E+00

1.35E+04

-1.22E-02

3.31E+04

3.26E-09

350E-6

1.72E-05

5.52E-09

9.54E-02

4.29E+01

-9.07E-01

-7.62E+01

1.47E+04

3.04E-02

2.213E+0

-1.01E+01

3.05E-17

1.17E-03

5.27E-01

1.58E+01

5.87E+03

2.03E+02

1.87E+03

11.81E+3

1.47E+04

480

7.43E-05

-9.51E+00

1.35E+04

-1.42E-02

4.49E+04

6.02E-09

350E-6

-3.27E-06

5.52E-09

9.54E-02

4.58E+01

-9.07E-01

-8.20E+01

1.71E+04

5.55E-02

2.213E+0

-1.03E+01

3.05E-17

1.17E-03

5.62E-01

1.58E+01

6.29E+03

2.33E+02

5.79E+03

11.81E+3

1.57E+04

510

7.43E-05

-9.51E+00

1.35E+04

-1.62E-02

5.86E+04

9.61E-09

350E-6

-2.37E-05

5.52E-09

9.54E-02

4.86E+01

-9.07E-01

-8.78E+01

1.96E+04

8.81E-02

2.213E+0

-1.05E+01

3.05E-17

1.17E-03

5.97E-01

1.58E+01

6.71E+03

2.65E+02

1.19E+04

11.81E+3

1.66E+04

Average

268.00

1.41E-04

-2.50E-01

3.66E+05

3.98E-07

3.50E-04

8.68E-07

5.69E+01

-7.47E+00

-6.28E+02

9.51E+04

1.52E+00

6.83E-01

3.90E-13

1.50E+01

3.38E+01

1.42E+03

8.18E+04

2.56E+03

5.31E+05

4.04E+02

Count

-6.82E-07

5.78E-07

-6.61E-03

2.22E-03

3.20E+01

7.99E+00

3.24E-04

9.04E-05

-7.10E+00

2.17E-01

3.40E+02

2.89E+02

&T&D

&8Worksheet by Michael Batley &T &D &"Symbol,Regular"&8Ó&"Arial,Regular" School of Chemistry Macquarie University

&8Worksheet by Michael Batley &"Symbol,Regular"&8Ó&"Arial,Regular" School of Chemistry Macquarie University

Graphs

slope=	-6.8E-07	±	6E-07
intercept=	3.24E-04	±	9E-05
Relative SE =	84.8%
slope=	-6.61E-03	±	2E-03
intercept=	-7.10E+00	±	2E-01
Relative SE =	33.5%
slope=	3.2E+01	±	8E+00
intercept=	3.40E+02	±	3E+02
Relative SE =	25.0%

Test for Zero Order

0 0 0 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 3.4996764342530437E-4 0 0 0 0 0 0 0 0 0 0 0 0 0 30 60 90 120 150 180 210 240 330 360 390 420 450 480 510 0 0 0 7.657142857142858E-4 4.6285714285714289E-4 1.3714285714285713E-4 4.0000000000000003E-5 5.7142857142857142E-5 5.1428571428571422E-5 6.2857142857142848E-5 5.7142857142857142E-5 6.8571428571428567E-5 6.2857142857142848E-5 5.7142857142857142E-5 7.4285714285714287E-5 7.4285714285714287E-5 7.4285714285714287E-5 7.4285714285714287E-5 0 0 0 0 0 0 0 0 0 0 0 0 0 30 60 90 120 150 180 210 240 330 360 390 420 450 480 510 0 0 0 3.0367627785058977E-4 2.8321288148286833E-4 2.6274948511514695E-4 2.4228608874742556E-4 2.2182269237970415E-4 2.0135929601198274E-4 1.8089589964426136E-4 1.6043250327653995E-4 9.9042314173375742E-5 7.8578917805654331E-5 5.8115521437932948E-5 3.7652125070211564E-5 1.7188728702490126E-5 -3.2746676652312579E-6 -2.3738064032952642E-5 0 0 0 0 0 0 0 0 0 0 0 0 0 Time / s

[Br2] / mol L-1

Test for First Order

0 0 0 0.21465107539161229 0.35510177904291412 1.1984685042698355 4.109034871782292 2.8763244102476047 3.1959160113862279 2.6148403729523682 2.8763244102476047 2.3969370085396711 2.6148403729523682 2.8763244102476047 2.2125572386520038 2.2125572386520038 2.2125572386520038 2.2125572386520038 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.21465107539161229 0.35510177904291412 1.1984685042698355 4.109034871782292 2.8763244102476047 3.1959160113862279 2.6148403729523682 2.8763244102476047 2.3969370085396711 2.6148403729523682 2.8763244102476047 2.2125572386520038 2.2125572386520038 2.2125572386520038 2.2125572386520038 0 0 0 0 0 0 0 0 0 0 0 0 0 30 60 90 120 150 180 210 240 330 360 390 420 450 480 510 0 0 0 -7.1747014529547393 -7.6780920982332121 -8.894487422557706 -10.126631103850338 -9.7699561599116063 -9.8753166755694313 -9.6746459801072806 -9.7699561599116063 -9.5876346031176514 -9.6746459801072806 -9.7699561599116063 -9.507591895444115 -9.507591895444115 -9.507591895444115 -9.507591895444115 0 0 0 0 0 0 0 0 0 0 0 0 0 30 60 90 120 150 180 210 240 330 360 390 420 450 480 510 0 0 0 -7.2963083413132139 -7.4945935115061051 -7.6928786816989971 -7.8911638518918892 -8.0894490220847803 -8.2877341922776733 -8.4860193624705644 -8.6843045326634556 -9.2791600432421308 -9.4774452134350238 -9.6757303836279149 -9.8740155538208079 -10.072300724013699 -10.27058589420659 -10.468871064399483 0 0 0 0 0 0 0 0 0 0 0 0 0 Time / s

ln([Br2] / mol L-1)

Test for Second Order

0 0 0 111.14519064557146 304.17970480595665 3464.7969500553509 40729.041698609821 19957.230432318822 24638.556089282498 16493.578869684978 19957.230432318822 13859.187800221403 16493.578869684978 19957.230432318822 11809.012090129478 11809.012090129478 11809.012090129478 11809.012090129478 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 111.14519064557146 304.17970480595665 3464.7969500553509 40729.041698609821 19957.230432318822 24638.556089282498 16493.578869684978 19957.230432318822 13859.187800221403 16493.578869684978 19957.230432318822 11809.012090129478 11809.012090129478 11809.012090129478 11809.012090129478 0 0 0 0 0 0 0 0 0 0 0 0 0 30 60 90 120 150 180 210 240 330 360 390 420 450 480 510 0 0 0 1305.9701492537313 2160.4938271604938 7291.666666666667 24999.999999999996 17500 19444.444444444445 15909.090909090912 17500 14583.333333333334 15909.090909090912 17500 13461.538461538461 13461.538461538461 13461.538461538461 13461.538461538461 0 0 0 0 0 0 0 0 0 0 0 0 0 30 60 90 120 150 180 210 240 330 360 390 420 450 480 510 0 0 0 1298.6374452202322 2257.7286866474383 3216.8199280746444 4175.911169501851 5135.0024109290571 6094.0936523562632 7053.1848937834693 8012.2761352106754 10889.549859492294 11848.6411009195 12807.732342346706 13766.823583773912 14725.914825201118 15685.006066628324 16644.09730805553 0 0 0 0 0 0 0 0 0 0 0 0 0 Time / s

[Br2]-1 / L mol-1

Test for Zero Order

[Br2] / mol L-1

Test for First Order

ln([Br2] / mol L-1)

Test for Second Order

[Br2]-1 / L mol-1

Test for Zero Order

[Br2] / mol L-1

Test for First Order

ln([Br2] / mol L-1)

Test for Second Order

[Br2]-1 / L mol-1