Kinetics lab report turnitin
Takeshi
KineticsofBrominationofAcetone1.xlsxData
| CHEM2201/6201: Kinetics of the Bromination of Acetone | ||||||
| Time / s | [Br2] / mol L-1 | Absorbance | Cuvette length (cm) | Epsilon (Lmol-1cm-1) | ||
| 30.00 | .00253 | 0.443 | 1 | 175 | ||
| 60.00 | .00243 | 0.425 | 1 | 175 | ||
| 90.00 | .00233 | 0.407 | 1 | 175 | ||
| 120.00 | .0022 | 0.385 | 1 | 175 | ||
| 150.00 | .00216 | 0.378 | 1 | 175 | ||
| 180.00 | .00199 | 0.348 | 1 | 175 | ||
| 210.00 | .00183 | 0.321 | 1 | 175 | ||
| 240.00 | .00165 | 0.288 | 1 | 175 | ||
| 330.00 | .0015 | 0.263 | 1 | 175 | ||
| 360.00 | .00137 | 0.239 | 1 | 175 | ||
| 390.00 | .00123 | 0.215 | 1 | 175 | ||
| 420.00 | .00108 | 0.189 | 1 | 175 | ||
| 450.00 | .00093 | 0.163 | 1 | 175 | ||
| 480.00 | .00078 | 0.137 | 1 | 175 | ||
| 510.00 | .00065 | 0.113 | 1 | 175 | ||
| 540.00 | .0005 | 0.087 | 1 | 175 | ||
| 570.00 | .00037 | 0.065 | 1 | 175 | ||
| 600.00 | .00022 | 0.039 | 1 | 175 | ||
&T&D
&8Worksheet by Michael Batley &"Symbol,Regular"&8Ó&"Arial,Regular" School of Chemistry Macquarie University
Working
| CHEM2201/6201: Kinetics of the Bromination of Acetone | |||||||||||||||||||||||||||||||||
| [Br2] / mol L-1 | Time / s | [Br2] / mol L-1 | ln([Br2] / mol L-1) | 1/[Br2] / mol L-1 | dxy | dx2 | syx | error | Y | W1 | W2 | x | lny | dxy | dx2 | syx | error | Y | W3 | W4 | x | 1/y | dxy | dx2 | syx | error | Y | ||||||
| .003 | 30 | 2.53E-03 | -5.98E+00 | 3.95E+02 | -3.18E-01 | 8.31E+04 | 2.47E-09 | 128.4E-6 | 2.58E-03 | 6.41E-06 | 2.49E+00 | 7.46E+01 | -1.49E+01 | -9.72E+01 | 5.07E+04 | 1.11E-02 | 121.2E-3 | -5.91E+00 | 4.11E-11 | 3.73E+00 | 1.12E+02 | 1.47E+03 | 2.55E+04 | 3.10E+04 | 3.23E+03 | 52.9E+0 | 3.66E+02 | ||||||
| .002 | 60 | 2.43E-03 | -6.02E+00 | 4.12E+02 | -2.58E-01 | 6.67E+04 | 1.07E-09 | 128.4E-6 | 2.46E-03 | 5.90E-06 | 2.29E+00 | 1.37E+02 | -1.38E+01 | -5.99E+01 | 2.91E+04 | 3.11E-03 | 126.4E-3 | -5.98E+00 | 3.48E-11 | 3.16E+00 | 1.90E+02 | 1.30E+03 | 1.13E+04 | 1.18E+04 | 4.44E+02 | 57.47E+0 | 4.00E+02 | ||||||
| .002 | 90 | 2.33E-03 | -6.06E+00 | 4.30E+02 | -2.04E-01 | 5.21E+04 | 2.52E-10 | 128.4E-6 | 2.34E-03 | 5.41E-06 | 2.10E+00 | 1.89E+02 | -1.27E+01 | -3.28E+01 | 1.44E+04 | 1.57E-04 | 132E-3 | -6.06E+00 | 2.93E-11 | 2.66E+00 | 2.39E+02 | 1.14E+03 | 3.32E+03 | 2.59E+03 | 4.78E+01 | 62.67E+0 | 4.34E+02 | ||||||
| .002 | 120 | 2.20E-03 | -6.12E+00 | 4.55E+02 | -1.53E-01 | 3.93E+04 | 4.77E-10 | 128.4E-6 | 2.22E-03 | 4.84E-06 | 1.88E+00 | 2.25E+02 | -1.15E+01 | -1.32E+01 | 5.25E+03 | 9.90E-05 | 139.5E-3 | -6.13E+00 | 2.34E-11 | 2.13E+00 | 2.55E+02 | 9.67E+02 | 4.07E+01 | 3.28E+00 | 4.16E+02 | 70.04E+0 | 4.69E+02 | ||||||
| .002 | 150 | 2.16E-03 | -6.14E+00 | 4.63E+02 | -1.23E-01 | 2.83E+04 | 3.35E-09 | 128.4E-6 | 2.10E-03 | 4.67E-06 | 1.81E+00 | 2.72E+02 | -1.11E+01 | -4.75E+00 | 9.45E+02 | 6.60E-03 | 142.1E-3 | -6.20E+00 | 2.18E-11 | 1.98E+00 | 2.97E+02 | 9.15E+02 | -3.97E+02 | 1.64E+03 | 3.14E+03 | 72.66E+0 | 5.03E+02 | ||||||
| .002 | 180 | 1.99E-03 | -6.22E+00 | 5.03E+02 | -7.72E-02 | 1.91E+04 | 3.87E-11 | 128.4E-6 | 1.98E-03 | 3.95E-06 | 1.53E+00 | 2.76E+02 | -9.55E+00 | 3.53E-01 | 7.86E+01 | 3.71E-03 | 154.3E-3 | -6.27E+00 | 1.56E-11 | 1.42E+00 | 2.56E+02 | 7.14E+02 | 2.75E+03 | 4.90E+03 | 1.67E+03 | 85.72E+0 | 5.37E+02 | ||||||
| .002 | 210 | 1.83E-03 | -6.30E+00 | 5.45E+02 | -4.38E-02 | 1.17E+04 | 8.01E-10 | 128.4E-6 | 1.86E-03 | 3.36E-06 | 1.31E+00 | 2.74E+02 | -8.23E+00 | -2.36E+00 | 1.80E+03 | 2.08E-03 | 167.3E-3 | -6.34E+00 | 1.13E-11 | 1.03E+00 | 2.16E+02 | 5.61E+02 | 6.86E+03 | 8.10E+03 | 7.10E+02 | 100.7E+0 | 5.71E+02 | ||||||
| .002 | 240 | 1.65E-03 | -6.41E+00 | 6.08E+02 | -1.69E-02 | 6.14E+03 | 9.43E-09 | 128.4E-6 | 1.74E-03 | 2.71E-06 | 1.05E+00 | 2.52E+02 | -6.74E+00 | -1.11E+01 | 4.74E+03 | 8.84E-06 | 186.5E-3 | -6.41E+00 | 7.34E-12 | 6.66E-01 | 1.60E+02 | 4.05E+02 | 1.09E+04 | 9.40E+03 | 2.36E+00 | 125.2E+0 | 6.06E+02 | ||||||
| .002 | 330 | 1.50E-03 | -6.50E+00 | 6.65E+02 | 8.48E-04 | 1.36E+02 | 1.42E-08 | 128.4E-6 | 1.38E-03 | 2.26E-06 | 8.77E-01 | 2.89E+02 | -5.70E+00 | -3.42E+01 | 2.16E+04 | 1.40E-02 | 204.2E-3 | -6.63E+00 | 5.10E-12 | 4.63E-01 | 1.53E+02 | 3.08E+02 | 1.89E+04 | 2.02E+04 | 8.68E+02 | 150.1E+0 | 7.09E+02 | ||||||
| .001 | 360 | 1.37E-03 | -6.60E+00 | 7.32E+02 | -2.69E-03 | 1.74E+03 | 1.04E-08 | 128.4E-6 | 1.26E-03 | 1.87E-06 | 7.24E-01 | 2.61E+02 | -4.77E+00 | -4.66E+01 | 2.54E+04 | 7.58E-03 | 224.7E-3 | -6.70E+00 | 3.48E-12 | 3.16E-01 | 1.14E+02 | 2.31E+02 | 1.98E+04 | 1.80E+04 | 3.67E+01 | 181.7E+0 | 7.43E+02 | ||||||
| .001 | 390 | 1.23E-03 | -6.70E+00 | 8.14E+02 | -1.44E-02 | 5.14E+03 | 7.14E-09 | 128.4E-6 | 1.14E-03 | 1.51E-06 | 5.86E-01 | 2.28E+02 | -3.93E+00 | -5.72E+01 | 2.76E+04 | 2.71E-03 | 249.8E-3 | -6.77E+00 | 2.28E-12 | 2.07E-01 | 8.07E+01 | 1.68E+02 | 1.91E+04 | 1.49E+04 | 2.78E+02 | 224.6E+0 | 7.77E+02 | ||||||
| .001 | 420 | 1.08E-03 | -6.83E+00 | 9.26E+02 | -3.56E-02 | 1.03E+04 | 3.10E-09 | 128.4E-6 | 1.02E-03 | 1.17E-06 | 4.53E-01 | 1.90E+02 | -3.09E+00 | -6.47E+01 | 2.77E+04 | 5.06E-05 | 284.2E-3 | -6.84E+00 | 1.36E-12 | 1.24E-01 | 5.19E+01 | 1.14E+02 | 1.68E+04 | 1.10E+04 | 1.61E+03 | 290.6E+0 | 8.12E+02 | ||||||
| .001 | 450 | 9.31E-04 | -6.98E+00 | 1.07E+03 | -6.57E-02 | 1.73E+04 | 7.21E-10 | 128.4E-6 | 9.05E-04 | 8.68E-07 | 3.37E-01 | 1.52E+02 | -2.35E+00 | -6.78E+01 | 2.59E+04 | 1.46E-03 | 329.5E-3 | -6.91E+00 | 7.53E-13 | 6.84E-02 | 3.08E+01 | 7.34E+01 | 1.36E+04 | 7.39E+03 | 3.54E+03 | 390.7E+0 | 8.46E+02 | ||||||
| .001 | 480 | 7.83E-04 | -7.15E+00 | 1.28E+03 | -1.05E-01 | 2.61E+04 | 3.89E-12 | 128.4E-6 | 7.85E-04 | 6.13E-07 | 2.38E-01 | 1.14E+02 | -1.70E+00 | -6.58E+01 | 2.24E+04 | 6.73E-03 | 392E-3 | -6.98E+00 | 3.76E-13 | 3.41E-02 | 1.64E+01 | 4.36E+01 | 9.88E+03 | 4.39E+03 | 5.38E+03 | 553.1E+0 | 8.80E+02 | ||||||
| .001 | 510 | 6.46E-04 | -7.35E+00 | 1.55E+03 | -1.50E-01 | 3.67E+04 | 3.75E-10 | 128.4E-6 | 6.65E-04 | 4.17E-07 | 1.62E-01 | 8.25E+01 | -1.19E+00 | -5.96E+01 | 1.84E+04 | 1.35E-02 | 475.3E-3 | -7.06E+00 | 1.74E-13 | 1.58E-02 | 8.05E+00 | 2.45E+01 | 6.62E+03 | 2.39E+03 | 6.35E+03 | 813E+0 | 9.15E+02 | ||||||
| .0 | 540 | 4.97E-04 | -7.61E+00 | 2.01E+03 | -2.07E-01 | 4.91E+04 | 2.32E-09 | 128.4E-6 | 5.45E-04 | 2.47E-07 | 9.59E-02 | 5.18E+01 | -7.30E-01 | -4.77E+01 | 1.29E+04 | 2.20E-02 | 617.3E-3 | -7.13E+00 | 6.11E-14 | 5.55E-03 | 3.00E+00 | 1.12E+01 | 3.58E+03 | 9.73E+02 | 6.26E+03 | 1.372E+3 | 9.49E+02 | ||||||
| .0 | 570 | 3.71E-04 | -7.90E+00 | 2.69E+03 | -2.66E-01 | 6.33E+04 | 2.93E-09 | 128.4E-6 | 4.26E-04 | 1.38E-07 | 5.35E-02 | 3.05E+01 | -4.23E-01 | -3.50E+01 | 8.45E+03 | 2.62E-02 | 826.3E-3 | -7.20E+00 | 1.90E-14 | 1.73E-03 | 9.85E-01 | 4.65E+00 | 1.72E+03 | 3.48E+02 | 5.05E+03 | 2.457E+3 | 9.83E+02 | ||||||
| .0 | 600 | 2.23E-04 | -8.41E+00 | 4.49E+03 | -3.40E-01 | 7.93E+04 | 6.88E-09 | 128.4E-6 | 3.06E-04 | 4.97E-08 | 1.93E-02 | 1.16E+01 | -1.62E-01 | -1.78E+01 | 3.52E+03 | 2.50E-02 | 1.377E+0 | -7.27E+00 | 2.47E-15 | 2.24E-04 | 1.34E-01 | 1.01E+00 | 4.31E+02 | 5.13E+01 | 2.70E+03 | 6.825E+3 | 1.02E+03 | ||||||
| Average | 318.33 | 1.43E-03 | -2.38E+00 | 5.96E+05 | 6.60E-08 | 1.28E-04 | 4.64E-05 | 1.73E+02 | -6.25E+00 | -7.17E+02 | 3.01E+05 | 1.46E-01 | 1.91E-01 | 1.98E-10 | 1.80E+01 | 1.21E+02 | 4.70E+02 | 1.71E+05 | 1.49E+05 | 4.17E+04 | 1.02E+02 | ||||||||||||
| Count | 18 | -3.99E-06 | 1.66E-07 | -2.38E-03 | 3.49E-04 | 1.14E+00 | 2.64E-01 | ||||||||||||||||||||||||||
| 2.70E-03 | 3.03E-05 | -5.84E+00 | 7.52E-02 | 3.31E+02 | 4.01E+01 | ||||||||||||||||||||||||||||
&T&D
&T&D
&T&D
&8Worksheet by Michael Batley &T &D &"Symbol,Regular"&8Ó&"Arial,Regular" School of Chemistry Macquarie University
&8Worksheet by Michael Batley &T &D &"Symbol,Regular"&8Ó&"Arial,Regular" School of Chemistry Macquarie University
&8Worksheet by Michael Batley &"Symbol,Regular"&8Ó&"Arial,Regular" School of Chemistry Macquarie University
Graphs
| slope= | -4.0E-06 | ± | 2E-07 | |||||||
| intercept= | 2.70E-03 | ± | 3E-05 | |||||||
| Relative SE = | 4.2% | |||||||||
| slope= | -2.38E-03 | ± | 3E-04 | |||||||
| intercept= | -5.84E+00 | ± | 8E-02 | |||||||
| Relative SE = | 14.6% | |||||||||
| slope= | 1.1E+00 | ± | 3E-01 | |||||||
| intercept= | 3.31E+02 | ± | 4E+01 | |||||||
| Relative SE = | 23.1% |
Test for Zero Order
0 0 0 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 0 0 0 0 0 0 0 0 0 0 0 0 0 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 1.2842935975465391E-4 0 0 0 0 0 0 0 0 0 0 30 60 90 120 150 180 210 240 330 360 390 420 450 480 510 540 570 600 0 0 0 2.5314285714285716E-3 2.4285714285714284E-3 2.3257142857142856E-3 2.2000000000000001E-3 2.16E-3 1.9885714285714285E-3 1.8342857142857143E-3 1.6457142857142855E-3 1.502857142857143E-3 1.3657142857142856E-3 1.2285714285714285E-3 1.08E-3 9.3142857142857144E-4 7.8285714285714287E-4 6.457142857142857E-4 4.9714285714285713E-4 3.7142857142857143E-4 2.2285714285714286E-4 0 0 0 0 0 0 0 0 0 0 30 60 90 120 150 180 210 240 330 360 390 420 450 480 510 540 570 600 0 0 0 2.5811056119453063E-3 2.4613539132623099E-3 2.3416022145793134E-3 2.2218505158963175E-3 2.102098817213321E-3 1.9823471185303246E-3 1.8625954198473282E-3 1.742843721164332E-3 1.383588625115343E-3 1.2638369264323466E-3 1.1440852277493504E-3 1.024333529066354E-3 9.0458183038335778E-4 7.8483013170036137E-4 6.6507843301736496E-4 5.4532673433436854E-4 4.2557503565137213E-4 3.0582333696837615E-4 0 0 0 0 0 0 0 0 0 0 Time / s
[Br2] / mol L-1
Test for First Order
0 0 0 0.1212388155395285 0.12637363596237913 0.13196264197545735 0.13950336437405489 0.14208676001061146 0.15433561863221593 0.16731711926483217 0.18648887251392757 0.20421595165023243 0.22472299282013028 0.24980835015819133 0.28417352002122293 0.32950181155835051 0.39203500207307396 0.47529907330983306 0.6173424745288637 0.82628915821555582 1.3771485970259265 0 0 0 0 0 0 0 0 0 0 0 0 0 0.1212388155395285 0.12637363596237913 0.13196264197545735 0.13950336437405489 0.14208676001061146 0.15433561863221593 0.16731711926483217 0.18648887251392757 0.20421595165023243 0.22472299282013028 0.24980835015819133 0.28417352002122293 0.32950181155835051 0.39203500207307396 0.47529907330983306 0.6173424745288637 0.82628915821555582 1.3771485970259265 0 0 0 0 0 0 0 0 0 0 30 60 90 120 150 180 210 240 330 360 390 420 450 480 510 540 570 600 0 0 0 -5.9789714828605156 -6.0204520839812341 -6.0637280674630558 -6.1192979186178666 -6.1376470572860633 -6.2203387731311768 -6.3011001297756355 -6.4095807727697052 -6.5003872207278866 -6.5960777009741403 -6.7019032247779879 -6.8307942378460087 -6.9787910520988889 -7.1525603270775262 -7.3451534341933105 -7.6066331342510676 -7.8981539830100136 -8.4089796067760041 0 0 0 0 0 0 0 0 0 0 30 60 90 120 150 180 210 240 330 360 390 420 450 480 510 540 570 600 0 0 0 -5.9121161498581163 -5.9835967210322627 -6.0550772922064082 -6.1265578633805546 -6.1980384345547002 -6.2695190057288457 -6.3409995769029921 -6.4124801480771376 -6.6269218615995751 -6.6984024327737206 -6.769883003947867 -6.8413635751220125 -6.912844146296159 -6.9843247174703045 -7.05580528864445 -7.1272858598185964 -7.1987664309927419 -7.2702470021668884 0 0 0 0 0 0 0 0 0 0 Time / s
ln([Br2] / mol L-1)
Test for Second Order
0 0 0 52.898373834533515 57.474064867285094 62.670181930789624 70.037125765919157 72.655111605591742 85.721800821222828 100.74875987862471 125.15978210182016 150.0853412172124 181.74144301838851 224.58091869450232 290.62044642236697 390.72802765077228 553.10634379313592 813.00438300989663 1371.5488131395653 2457.1012938824542 6825.2813718957059 0 0 0 0 0 0 0 0 0 0 0 0 0 52.898373834533515 57.474064867285094 62.670181930789624 70.037125765919157 72.655111605591742 85.721800821222828 100.74875987862471 125.15978210182016 150.0853412172124 181.74144301838851 224.58091869450232 290.62044642236697 390.72802765077228 553.10634379313592 813.00438300989663 1371.5488131395653 2457.1012938824542 6825.2813718957059 0 0 0 0 0 0 0 0 0 0 30 60 90 120 150 180 210 240 330 360 390 420 450 480 510 540 570 600 0 0 0 395.0338600451467 411.76470588235298 429.97542997543002 454.5454545454545 462.96296296296293 502.87356321839081 545.17133956386294 607.63888888888891 665.39923954372614 732.21757322175733 813.95348837209303 925.92592592592587 1073.6196319018404 1277.3722627737227 1548.6725663716813 2011.4942528735633 2692.3076923076924 4487.1794871794873 0 0 0 0 0 0 0 0 0 0 30 60 90 120 150 180 210 240 330 360 390 420 450 480 510 540 570 600 0 0 0 365.59870021280153 399.90686768611789 434.21503515943431 468.52320263275067 502.83137010606708 537.1395375793835 571.4477050526998 605.75587252601622 708.68037494596547 742.98854241928188 777.2967098925983 811.6048773659146 845.91304483923102 880.22121231254744 914.52937978586385 948.83754725918016 983.14571473249657 1017.453882205813 0 0 0 0 0 0 0 0 0 0 Time / s
[Br2]-1 / L mol-1
