Solar Cells 2

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class05SolarCells2020-08Resistanceeffectsonfillfactor.pptx

Resistance effects on fill factor

Prof. Richard R. King

Solar Cells

EEE 565

Arizona State University

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h =

Iinc

Voc

Jsc

FF

h = solar cell efficiency (unitless)

Voc = open-circuit voltage (V)

Jsc = short-circuit current (A/cm2)

FF = fill factor (unitless)

Iinc = incident light intensity (W/cm2)

FF

Solar Cell Efficiency

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(a) Generation-recombination current region

(b) Diffusion current region (g = 1)

(c) High-injection region (g = 2)

(d) Series resistance effect

(e) Reverse leakage current

Ref.: S. M. Sze, Physics of Semiconductor Devices, 2nd Ed., Wiley, New York, 1981.

Dark I-V

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γ = 1, ρs = 0 Ωcm2, σsh = 0 Ω-1cm-2

γ = 2, ρs = 0 Ωcm2, σsh = 0 Ω-1cm-2

γ = 1, ρs = 2 Ωcm2, σsh = 0 Ω-1cm-2

γ = 1, ρs = 0 Ωcm2, σsh = 0.007 Ω-1cm-2

γ = 1, ρs = 2 Ωcm2, σsh = 0.007 Ω-1cm-2

Effects of diode ideality factor, series resistance, and shunt conductance on FF

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Fill factor

A useful approximation for FF when you know

Voc and g , in the absence of series resistance and shunt conductance, is:

M. A. Green, High Efficiency Silicon Solar Cells, Trans Tech Publications, Brookfield, VT, 1987.

M. A. Green, "Accuracy of Analytical Expressions for Solar Cell Fill Factors," Solar Cells 8, 3 (1983)

where:

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Diode equation with non-ideal shunt,

series resistance effects

ρs = specific series resistance [Ωcm2]

σsh = specific shunt conductance [Ω-1cm-2]

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Diode Equation with Non-Ideal Shunt, Series Resistance Effects (series after shunt)

rs = specific series resistance [Wcm2]

ssh = specific shunt conductance [W-1cm-2]

Go crazy, include everything:

1-diode model, with series, with shunt

1-diode model, with series resistance

2-diode model, no series, no shunt

1-diode model, no series, no shunt

ρs

σsh

Joγ

+V

0

J

(V + Jρs )

Jo1

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High series resistance affects both the dark I-V and the light I-V, degrading the fill factor and reducing efficiency

Effect of high series resistance

Rs= 10 

Rs= 1 

A= 1 cm2

Effect of Rseries

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8

High series resistance and low shunt resistance degrade primarily FF, but in severe cases, Voc and possibly Jsc. Due to edge leakage, defects shorting the junction, etc.

Effect of low shunt resistance

Effect of Rshunt

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9

γ = 1, ρs = 0 Ωcm2, σsh = 0 Ω-1cm-2

γ = 2, ρs = 0 Ωcm2, σsh = 0 Ω-1cm-2

γ = 1, ρs = 2 Ωcm2, σsh = 0 Ω-1cm-2

γ = 1, ρs = 0 Ωcm2, σsh = 0.007 Ω-1cm-2

γ = 1, ρs = 2 Ωcm2, σsh = 0.007 Ω-1cm-2

Effects of diode ideality factor, series resistance, and shunt conductance on FF

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Effects of diode ideality factor, series resistance, and shunt conductance on FF

Diode ideality factor > 1 results in a more rounded “knee” of the light J-V curve, near Vmp and Jmp

High series resistance results in a sloped voltage leg of the light J-V curve, near Voc

High shunt conductance results in a sloped current leg of the light J-V curve, near Jsc

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Example for a (very) good silicon solar cell

Note that Voc and Jsc stay the same or change very little for the different values of diode ideality factor, specific series resistance, and specific shunt conductance shown here

Effects of diode ideality factor, series resistance, and shunt conductance on FF

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Resistance in different cell regions

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Typical solar cell structure

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Base resistance

Emitter spreading resistance

Contact resistance

Metal grid resistance

Sources of series resistance

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Base resistance is just the resistance due to flow of current in the neutral base region

where b is the resistivity of the base region, typically 0.5- 5.0 -cm, and Wb is the width of the base.

For a 200 m base length cell, and 1 -cm resistivity material, for a 1 cm2 cell, the base resistance would be 0.02 , quite small

Base resistance

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Emitter spreading resistance is due to distributed resistance along the emitter to the front grid contacts

The emitter is typically quite thin. Therefore its more usual to talk about the sheet resistance of the emitter in terms of

where sh is the sheet resistance in ohms/square (/)

Emitter spreading resistance

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The incremental power loss in a section dy is

The current flowing into the left finger is zero in the middle and increases linearly as y increases

The total power loss due to the current flowing into the left finger is

Emitter spreading resistance

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At the maximum power point, the generated power is given by

Therefore, the fractional power loss is given by

As S increases as well as sheet resistance, so does fractional power loss. For sh = 40 /, Jmp = 30 mA/cm2, Vmp = 450 mV, S < 4 mm for less than 4% total power loss

Optimal grid design minimizes power loss while simultaneously minimizing shading loss

Emitter spreading resistance

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Due to non-ideal nature of metal semiconductor contact

Usually characterized in terms of the specific contact resistance

Typical values on the order of 10-4-10-6 -cm2

Contact resistance reduced by heavy doping under contact: tunnel contact

Contact resistance

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0.000.010.020.030.040.0500.10.20.30.40.50.60.70.8Current Density (A/cm2)Voltage (V)g=1, Rs=0, Ssh=0g=2, Rs=0, Ssh=0g=1, Rs=2, Ssh=0g=1, Rs=0, Ssh=0.007g=1, Rs=2, Ssh=0.007

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