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Chapter12.pptx

Chapter 12 – Solid & Liquid Wastes

Learning Objectives

By the end of this chapter, the reader will be able to:

Describe trends in the production of solid waste

Discuss methods for source reduction of solid waste

Discuss the role of landfills for disposing of solid waste

Describe methods for primary, secondary, and tertiary sewage treatment

Discuss hazards of poorly designed solid waste disposal sites and improperly processed sewage

Two Major Challenges

Disposal of Solid Wastes

History of disposal methods

Challenges of growing volume of waste

Proposed solutions

Treatment & Processing of Liquid Wastes

Human solid wastes (sewage)

Animal wastes

~4.5 pounds per person, per day

Hierarchy for Managing Waste

Source Reduction (best)

Recycling

Energy Recovery

Disposal (worst)

Hierarchy for Managing Waste

Source Reduction (best)

Recycling

Energy Recovery

Disposal (worst)

Reducing the amount of waste created

Strategies:

Reusing/donating items

Buying in bulk (less packaging)

Reducing packaging (e.g. water bottles)

Redesigning products

Reducing toxicity of materials produced

Hierarchy for Managing Waste

Source Reduction (best)

Recycling

Energy Recovery

Disposal (worst)

Sorting and processing recyclable products into raw materials

Then remanufacturing with the recycle materials

Benefits:

Preventing emissions

Saving energy

Supplying valuable raw materials

Creating jobs

Conserving resources

What’s the recycling rate in Houston?

Only 6%... The “diversion rate” is 19%,

but 13% of this is yard waste

One Bin to Rule Them All..?

Houston has an abysmal recycling rate – approximately 17 percent diversion rate (only 6 percent came from recycling, the rest from yard waste disposal)

Compared to San Francisco at ~80 percent diversion rate

In 2013, the City of Houston won a $1M grant under a program to spur municipal innovation – the Bloomberg Philanthropies Mayors Challenge

Awarded for a “One Bin” approach to recycling – all trash (recyclable and not) would be combined in one bin

Sounded a lot like… trash, actually

One Bin to Rule Them All..?

One bin program looked a lot like a Dirty MRF (materials recovery facility)

The vendor for the City of Houston claimed it was not just a MRF

A Clean MRF accepts only recyclables

Can recover from 5 to 45% of materials as recyclables

The rest is still landfilled

In the end, Mayor Sylvester Turner decided against a one bin approach, and opted for a more traditional approach to recycling with separate waste and recycling streams

Hierarchy for Managing Waste

Source Reduction (best)

Recycling

Energy Recovery

Disposal (worst)

Convert non-recyclable waste materials into energy (heat, electricity, or fuel), called “waste-to-energy”

Processes:

Combustion

Gasification (convert to gas without combustion)

Pyrolization (decomposition of organic materials)

Anaerobic digestion

Landfill gas

Hierarchy for Managing Waste

Source Reduction (best)

Recycling

Energy Recovery

Disposal (worst)

Treatment to reduce volume & toxicity

Can be physical, chemical, or biological

Landfills are the most common form of waste disposal

Methane gas may be produced and trapped (form of energy recovery)

Wastes & the Three P’s

Population

Pollution

Poverty

Hazardous Wastes

Regulated by the Resource Conservation and Recovery Act (RCRA) of 1976

Characterized by the following four traits:

Ignitability

Reactivity

Corrosivity

Toxicity

Additionally, RCRA includes listed hazardous wastes

CERCLA (what is this act usually referred to as?)

Provided for the clean-up and remediation of sites with hazardous waste

Household Hazardous Waste (HHW)

In general, legal for most households to dispose of HHW as normal, municipal solid waste

Modern landfills are designed to handle normal amounts of HHW

Some examples:

Paints/solvents

Motor oil, gasoline

Pesticides

Products with Mercury

Batteries

Aerosols

Cleaning agents

2nd Major Problem – Treatment & Processing of Liquid Waste

What do we already know about this?

Pliny, the Elder

Philosopher, author, military commander

Most notable for writing Naturalis Historia, a 37-book encyclopedia

Commented in Natural History that Roman sewage systems, among all the things the Romans had accomplished, were “the most noteworthy of all”

Roman Sewer Systems

Poorer quality water from aqueducts was used for latrines and public baths

Sewers covered by stones that flushed waste from latrines and bath houses to nearby rivers (in Rome, the Tiber)

First sewers built between 800 and 735 BCE

Latrines – public and private – were built

Around 100 AD, homes were directly connected to sewage systems

By then, after 900 years of development, the sewage system was very efficient

Cloaca Maxima – one of the earliest sewage systems; drained low-lying marshes, as well as sewage from Rome

Waste and Antimicrobial Resistance (AR)

What is antimicrobial resistances?

Scope of the problem

Accounts for ~50,000 deaths in United States and Europe

Estimates as high as 700,000 worldwide

Projected to be as high as 10M by 2050

Pharmaceutical waste and agriculture animal waste are major contributors to the issue

Pharmaceutical Waste

Waste can include pharmaceutical drugs, such as antibiotics

Minor source of pharmaceutical waste is from patients disposing drugs

Major sources is from the production of the active ingredients in drugs

India exports ~20% of the world’s generic drugs; China exports more than 60% of active pharmaceutical agents

Hyderabad, India has 90 pharmaceutical companies that discharge ~400,000 gallons of wastewater daily

Antibiotics in India’s Wastewater

Antibiotics in India’s Wastewater

Ciprofloxacin was found at concentrations higher than patient’s blood

As high as 31 mg/L

In one day, as much ciprofloxacin was disposed of in Hyderabad’s water as used in Sweden for 5 days (to treat ~44,000 individuals)

Researchers found drug-resistant genes in downstream sites

Almost 2% of DNA samples had resistant genes

Not just India…

Tamiflu in the Rhine River

Tetracycline & penicillin in China

Bacitracin in Norway

Hospital waste water throughout the world

Antibiotics and Farm Animals

~80% of antibiotics (by weight) are given to farm animals

Administered in low doses in food and water

Promotes growth and to prophylactically avoid infections that would be rampant in the modern factory farm

Natural Resources Defense Council report found that the FDA had allowed 30 potentially harmful antibiotics (18 classified as “high risk” by the FDA) to be used as additives to animal food and water

A review in 2001 found that 26 of the 30 did not even meet 1973 safety criteria

None of the 30 would meet current guidelines

However, 28 are still approved for use, 9 of which are still being actively marketed

The European Union has banned all antibiotic use as growth promoters

Denmark has banned all prophylactic use

Questions?