Carbon footprint
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Ecosystems: Biogeochemical Cycles
The Disruption of the Carbon Cycle
Nutrients cycle through ecosystems
Nutrients cycle through ecosystems.� �
Nutrients flow from sink to sink.
Nutrients cycle through ecosystems.� �
Nutrients flow from sink to sink.� �
Biogeochemical � �
Nutrient flows are generated by organisms and geological processes.�
�
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The Carbon Cycle
The alteration of a biogeochemical cycle
Three patterns 1) Increase in airborne carbon as CO2 2) Increase in global temperature 3) Ocean acidification Mechanism - What is the link?
The Carbon Cycle
Terrestrial Components +
Ocean Components +
Geological Sinks
The Carbon Cycle
Terrestrial Components
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Carbon Cycle - Biological Carbon Cycle - Biological
Carbon cycle • Atmosphere contains large sink of C as
CO2
Carbon Cycle - Biological
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Carbon cycle • Atmosphere contains sink of C as CO2 • Plants absorb CO2 via photosynthesis and
convert it to carbohydrates
Carbon Cycle - Biological
Carbon cycle • Atmosphere contains sink of C as CO2 • Plants absorb CO2 via photosynthesis and
convert it to carbohydrates • Animals metabolize carbohydrates and
release C as CO2
Important terrestrial carbon sinks include
Forests
Peatlands Permafrost
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Forests
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Peatlands
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Permafrost
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The Carbon Cycle
Terrestrial Components +
Ocean Components
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Carbon cycle • Atmosphere contains sink of C as CO2 • Plants absorb CO2 via photosynthesis and
convert it to carbohydrates • Animals metabolize carbohydrates and
release C as CO2 • Sea surface absorbs and releases CO2 into
atmospheric sink.
Carbon cycle • Atmosphere contain large sink of C as CO2 • Plants absorb CO2 and via photosynthesis convert
it to carbohydrates • Animals metabolize carbohydrates and release C
as CO2 • Sea surface absorbs and releases CO2 into
atmospheric sink. • Marine organisms use C to build their bodies. In
addition C cycles through oceans in several forms.
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The Carbon Cycle
Terrestrial Components +
Ocean Components +
Geological Sinks
Geological sinks
Over long periods of time
1) Biological carbon is converted to coal, oil, and gas
2) Marine organisms die and become ocean sediments and eventually turn
into rocks (limestone, etc).
Carbon cycle • Atmosphere contain large sink of C as CO2 • Plants absorb CO2 and via photosynthesis convert it to
carbohydrates • Animals metabolize carbohydrates and release C as CO2 • Sea surface absorbs and releases CO2 into atmospheric
sink. • Marine organisms use C to build their bodies. In addition C
cycles through oceans in several forms. • Carbon is sequestered as fossil fuels and in ocean
sediments.
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Carbon cycle • Atmosphere contain large sink of C as CO2 • Plants absorb CO2 and via photosynthesis convert it to
carbohydrates • Animals metabolize carbohydrates and release C as CO2 • Sea surface absorbs and releases CO2 into atmospheric
sink. • Marine organisms use C to build their bodies. In addition C
cycles through oceans in several forms. • Carbon is sequestered as fossil fuels and in ocean
sediments. • Humans release stored C by burning fossil fuels and cutting
down forests.
Carbon Cycle - Key Points • Carbon cycles through several compartments
– Atmosphere – Oceans – Biological – Geological
• Some carbon is sequestered into sinks • Humans are releasing carbon from geological
sink faster then it is returned and can be absorbed by oceans.
Which of the following are human generated sources of carbon that could increase atmospheric levels of CO2? 1. Driving a gasoline powered car. 2. Riding a bicycle. 3. Exhaling during breathing. 4. All of the above. 5. None of the above.
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Carbon Cycle - Biological
How have atmospheric CO2 concentrations changed over time?
Ice-core Data
Atmospheric Gases
Isotopic Ratios - Temperature
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800,000 year CO2 trend
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Mauna Loa
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Why is there a yearly cycle � in CO2 levels?
Why is there a yearly cycle in CO2 levels?
• Fall/Winter CO2 released via decomposition.
• Spring/Summer CO2 absorbed via photosynthesis.
• Greater land area in northern versus southern hemisphere.
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800,000 year CO2 trend
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800,000 year CO2 trend
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400 ppm
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Since 1880
280 ppm to 405 ppm
125 ppm change
During ice ages 100 ppm change took 10,000’s of years
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Volcanoes and CO2
Calbuco volcano in Chile
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Volcanoes and CO2 • When volcanoes release magma this
also release CO2 and other gases (SO2, etc.)
• The best estimate is that volcanoes produce about 200 million tons of CO2 annually.
• Humans produce about 26.8 billion tons of CO2 annually.
• Volcanoes produce less than 1% of what humans do. 49
How do we know the CO2 is from human activity?
How do we know the CO2 is from human activity?
1) Correlation between CO2
increase and increase in use of fossils fuels.
But correlation is not causation!
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How do we know the CO2 is from
human activity?
1) Correlation between CO2 increase and increase in use of
fossils fuels.
2) Isotope signature of atmospheric CO2.
Isotopes
Same element, different number of neutrons.
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Hydrogen Deuterium Tritium
Isotopic signature of CO2 from fossil fuels
• Common isotopes of carbon are 12C and 13C. • Plants have a preference for the lighter isotopes (12C vs. 13C); thus they have lower 13C/12C ratios. • Since fossil fuels are ultimately derived from ancient plants, plants and fossil fuels all have roughly the same 13C/12C ratio – about 2% lower than that of the atmosphere. • As CO2 from these materials is released into, and mixes with, the atmosphere, the average 13C/12C ratio of the atmosphere decreases.
Why is the amount of CO2 increasing?
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Carbon balance
carbon released into atmosphere minus (carbon absorbed by land, ocean sinks, and geological sinks) = carbon left as C in the atmosphere
Carbon emitted
P = 1,000,000,000,000,000
Carbon released into atmosphere
Carbon emitted
Carbon absorbed land
Carbon absorbed ocean
P = 1,000,000,000,000,000
Minus carbon absorbed by land and ocean sinks
Carbon emitted
Carbon Atmosphere
P = 1,000,000,000,000,000
Equals what’s left as C in the atmosphere
Carbon absorbed land
Carbon absorbed ocean
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Currently where does the CO2 that humans emit end up?
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Fate of Anthropogenic CO2 Emissions (2000-2008)
Le Quéré et al. 2009, Nature Geoscience; Canadell et al. 2007, PNAS, updated
1.4 PgC y-1
+ 7.7 PgC y-1 3.0 PgC y-1
29%
4.1 PgC y-1
45%
26% 2.3 PgC y-1
Fate of Anthropogenic CO2 Emissions (2000-2008)
Le Quéré et al. 2009, Nature Geoscience; Canadell et al. 2007, PNAS, updated
1.4 PgC y-1
+ 7.7 PgC y-1 3.0 PgC y-1
29%
4.1 PgC y-1
45%
26% 2.3 PgC y-1
55% absorbed by natural systems
Fate of Anthropogenic CO2 Emissions (2000-2008)
Le Quéré et al. 2009, Nature Geoscience; Canadell et al. 2007, PNAS, updated
1.4 PgC y-1
+ 7.7 PgC y-1 3.0 PgC y-1
29%
4.1 PgC y-1
45%
26% 2.3 PgC y-1
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How long does CO2 stay in the atmosphere?
What are the predictions for future emissions?
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Sources of uncertainty with large potential consequences
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Feedbacks and Tipping Points
Arctic carbon sinks
Arctic methane sinks
Arctic Greenhouse Sinks • Permafrost stores large amounts of organic
carbon
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Arctic Greenhouse Sinks • Permafrost stores large amounts of organic
carbon • As permafrost melts biological decay releases
– CO2 – Methane
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Melting Permafrost
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Arctic Greenhouse Sinks • Permafrost stores large amounts of organic
carbon • As permafrost melts biological decay releases
– CO2 – Methane
• Methane hydrates - frozen methane
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Methane Hydrates
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Arctic Greenhouse Sinks • Permafrost stores large amounts of organic
carbon • As permafrost melts biological decay releases
– CO2 – Methane
• Methane hydrates - frozen methane • Boreal forest fires
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Boreal Forest Fires
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Arctic Greenhouse Sinks • Permafrost stores large amounts of organic
carbon • As permafrost melts biological decay releases
– CO2 – Methane
• Methane hydrates - frozen methane • Boreal forest fires • Release of all acts as feedbacks to warming • If enough warming occurs a run-away process of
CO2 and methane release could begin, that would take 1000’s of years to reverse.
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