experiment chimestry ( Spectroscopy and atomic spectra)
Name
Draft1
Table 1 –Observable Helium emission lines in the visible spectrum
|
Scale reading |
Color |
Observation |
Experiment (nm)+10% |
Literate value |
Error% |
λ (nm) |
|
44 |
Red |
2- Bright - Dull |
667.03 |
667.81 |
1.1% |
667.8 |
|
30 |
Yellow |
1 Bright |
586.77 |
587.6 |
1.4% |
587.6 |
|
16 |
Green |
2 Bright |
506.51 |
501.6 |
0.00% |
501.6 |
|
10 |
Blue |
1 Dull |
472.11 |
471.3 |
-1.7% |
471.3 |
|
5 |
Purple |
1 Bright |
443.45 |
447.1 |
8.1% |
447.1 |
Figure 1 – Calibration Plot for Helium
Equation 1: λ(nm) = 5.7331*( scale reading) +414.68
Table 5.4 H-Atom Spectrum Results:
|
N1 |
N2 |
Theoretical λ(nm) |
Scale reading |
Exp λ(nm) |
% error |
|
1 |
2 |
121 |
Experimentally not observable (UV) |
||
|
1 |
3 |
102 |
|
||
|
1 |
4 |
97 |
|
||
|
2 |
3 |
656 |
42 (RED) |
655.4 |
0.0% |
|
2 |
4 |
486 |
11 (BLUE) |
477.7 |
0.02% |
|
2 |
5 |
434 |
7 (PURPLE) |
454.8 |
0.05% |
|
2 |
6 |
410 |
|
|
|
|
3 |
4 |
1875 |
Experimentally not observable (IR) |
||
|
3 |
5 |
1282 |
|
||
|
3 |
6 |
1084 |
|
||
|
Theory |
Measurement |
Calibration/Calculation |
|
*To calculate the Error, use exp λ (nm) as,
Exp λ (nm) % error = * 100
Table 5.5 Wavelength Observations for Mercury (Hg)
|
Scale reading |
Color |
Observation |
Expt. λ (nm) |
Literature value (nm) |
% Error |
|
5 |
Purple |
1-Bright |
443.34 |
435.84 |
0.01% |
|
12 |
Green |
1-6 Bright |
483.47 |
546.07 |
0.11% |
|
28 |
Yellow |
1- Dull |
575.20 |
579.06 |
1.4% |
Table 4 – Krypton (Nobel Gas):
|
Scale reading |
Color |
Observation |
Expt. λ (nm) |
Literature value (nm) |
% Error |
|
25 |
Yellow/Green |
Bright/thin |
558 |
568.2 |
0.01% |
|
15 |
Orange |
Bright/thin |
500.6 |
647.1 |
0.2% |
|
4 |
Purple |
Dull/multi 2-3 |
437.6 |
413.1 |
0.05% |
Table 5 – General Observation on the Color
|
Nobel gases |
Color |
Observaton |
|
Xenon |
Purple, Blue |
Dull - 6 |
|
Krypton |
Yellow, Green, Orange, Purple |
Bright/thin and Dull 2-3 line |
|
Neon |
Red, Orange, Yellow, Blue, Light Blue |
Multi lines Bright colors and Dull |
|
Argon |
Purple, Green, Yellow, Red |
Dull |
Websites I have to site
https://ehs.ucr.edu/laser/wavelength.html site:
http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/atspect2.html
y
44.0 30.0 16.0 10.0 5.0 667.8 587.6 501.6 471.3 447.1
scale reading
wave length